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Free N‐heterocyclic carbenes from Brønsted acidic ionic liquids: Direct detection by electrospray ionization mass spectrometry

RATIONALE: The occurrence of N‐heterocyclic carbenes in imidazolium‐based ionic liquids has long been discussed, but no spectroscopic evidence has been reported yet due to their transient nature. The insertion of an ionizable acid group into the cation scaffold of an ionic liquid which acts as a cha...

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Detalles Bibliográficos
Autores principales: Salvitti, Chiara, Pepi, Federico, Managò, Marta, Bortolami, Martina, Michenzi, Cinzia, Chiarotto, Isabella, Troiani, Anna, de Petris, Giulia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542177/
https://www.ncbi.nlm.nih.gov/pubmed/35729083
http://dx.doi.org/10.1002/rcm.9338