Cargando…

Mechanistic Differences between Electrochemical Hydrogenation and Hydrogenolysis of 5‐Hydroxymethylfurfural and Their pH Dependence

Hydrogenation and hydrogenolysis are two important reactions for electrochemical reductive valorization of biomass‐derived oxygenates such as 5‐hydroxymethylfurfural (HMF). In general, hydrogenolysis (which combines hydrogenation and deoxygenation) is more challenging than hydrogenation (which does...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yuan, Xin, Lee, Kwanpyung, Bender, Michael T., Schmidt, J. R., Choi, Kyoung‐Shin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542785/ https://www.ncbi.nlm.nih.gov/pubmed/35731931 http://dx.doi.org/10.1002/cssc.202200952

Ejemplares similares

Hydrogenation versus hydrogenolysis during alkaline electrochemical valorization of 5-hydroxymethylfurfural over oxide-derived Cu-bimetallics
por: Hauke, Philipp, et al.
Publicado: (2023)

Tuning the Selectivity of the Hydrogenation/Hydrogenolysis of 5‐Hydroxymethylfurfural under Batch Multiphase and Continuous‐Flow Conditions
por: Rodríguez‐Padrón, Daily, et al.
Publicado: (2022)

Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran Over a Modified CoAl-Hydrotalcite Catalyst
por: Xia, Jing, et al.
Publicado: (2022)

Tailoring the catalytic performance of Cu/SiO(2) for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to renewable fuels
por: Jia, Hongyan, et al.
Publicado: (2022)

A unique Co@CoO catalyst for hydrogenolysis of biomass-derived 5-hydroxymethylfurfural to 2,5-dimethylfuran
por: Xiang, Shuang, et al.
Publicado: (2022)

Effect of pH on the Electrochemical Behavior of Hydrogen Peroxide in the Presence of Pseudomonas aeruginosa
por: Espinoza-Vergara, Javier, et al.
Publicado: (2021)

Non Noble-Metal Copper–Cobalt Bimetallic Catalyst for Efficient Catalysis of the Hydrogenolysis of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran under Mild Conditions
por: Zhang, Qingtu, et al.
Publicado: (2021)

On‐DNA Transfer Hydrogenolysis and Hydrogenation for the Synthesis of DNA‐Encoded Chemical Libraries
por: Stanway‐Gordon, Harriet A., et al.
Publicado: (2021)

Formic Acid‐Assisted Selective Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran over Bifunctional Pd Nanoparticles Supported on N‐Doped Mesoporous Carbon
por: Hu, Bin, et al.
Publicado: (2021)

Mechanistic insights into pH-dependent H(2) photoproduction in bisulfite-treated Chlamydomonas cells
por: Wei, Lanzhen, et al.
Publicado: (2020)

Insights into the Electrochemical Reduction of 5‐Hydroxymethylfurfural at High Current Densities
por: de Luna, Giancosimo Sanghez, et al.
Publicado: (2022)

Catalytic Hydrogenolysis of Polyolefins into Alkanes
por: Sánchez-Rivera, Kevin L., et al.
Publicado: (2020)

Electrochemical Oxidation of HMF via Hydrogen Atom Transfer and Hydride Transfer on NiOOH and the Impact of NiOOH Composition
por: Bender, Michael T., et al.
Publicado: (2022)

Cation- and pH-Dependent Hydrogen Evolution and Oxidation Reaction Kinetics
por: Huang, Botao, et al.
Publicado: (2021)

CMOS electrochemical pH localizer-imager
por: Jung, Han Sae, et al.
Publicado: (2022)

Recent progress, trends, and new challenges in the electrochemical production of green hydrogen coupled to selective electrooxidation of 5-hydroxymethylfurfural (HMF)
por: Gidi, Leyla, et al.
Publicado: (2023)

Unravelling the pH-dependence of a molecular photocatalytic system for hydrogen production
por: Reynal, Anna, et al.
Publicado: (2015)

Crystal structure of the Na(+)/H(+) antiporter NhaA at active pH reveals the mechanistic basis for pH sensing
por: Winkelmann, Iven, et al.
Publicado: (2022)

Metal Nanoparticles Immobilized on Molecularly Modified Surfaces: Versatile Catalytic Systems for Controlled Hydrogenation and Hydrogenolysis
por: Bordet, Alexis, et al.
Publicado: (2021)

Selective electrocatalytic hydrogenation of lignocellulose-derived 5-hydroxymethylfurfural with superior productivities
por: Zhang, Dingyi, et al.
Publicado: (2023)

Advances in Selective Electrochemical Oxidation of 5‐Hydroxymethylfurfural to Produce High‐Value Chemicals
por: Guo, Lei, et al.
Publicado: (2022)

Toward Mechanistic Design of Surrogate Buffers for Dissolution Testing of pH-Dependent Drug Delivery Systems
por: Blechar, Johannes Andreas, et al.
Publicado: (2020)

Evidence for the adaptation of protein pH-dependence to subcellular pH
por: Chan, Pedro, et al.
Publicado: (2009)

Synthesis and mechanistic investigations of pH-responsive cationic poly(aminoester)s
por: Blake, Timothy R., et al.
Publicado: (2020)

Self-supported hydrogenolysis of aromatic ethers to arenes
por: Meng, Qinglei, et al.
Publicado: (2019)

Unravelling pH Changes in Electrochemical Desalination with Capacitive Deionization
por: Arulrajan, Antony C., et al.
Publicado: (2021)

Inhibition of Candida albicans by Fluvastatin Is Dependent on pH
por: Schmidt, Martin, et al.
Publicado: (2009)

DNAzyme-Amplified Electrochemical Biosensor Coupled with pH Meter for Ca(2+) Determination at Variable pH Environments
por: Wang, Hui, et al.
Publicado: (2021)

pH-Dependent transfer hydrogenation or dihydrogen release catalyzed by a [(η(6)-arene)RuCl(κ(2)-N,N-dmobpy)](+) complex: a DFT mechanistic understanding
por: Luo, Chenguang, et al.
Publicado: (2020)

Universal dependence of hydrogen oxidation and evolution reaction activity of platinum-group metals on pH and hydrogen binding energy
por: Zheng, Jie, et al.
Publicado: (2016)

Mechanistic Analysis of Cocrystal Dissolution as a Function of pH and Micellar Solubilization
por: Cao, Fengjuan, et al.
Publicado: (2016)

Single-catalyst high-weight% hydrogen storage in an N-heterocycle synthesized from lignin hydrogenolysis products and ammonia
por: Forberg, Daniel, et al.
Publicado: (2016)

IRMOF-74(n)–Mg: a novel catalyst series for hydrogen activation and hydrogenolysis of C–O bonds
por: Stavila, Vitalie, et al.
Publicado: (2019)

Low energy carbon capture via electrochemically induced pH swing with electrochemical rebalancing
por: Jin, Shijian, et al.
Publicado: (2022)

Mechanistic understanding of humin formation in the conversion of glucose and fructose to 5-hydroxymethylfurfural in [BMIM]Cl ionic liquid
por: Xu, Zhanwei, et al.
Publicado: (2020)

Esophageal pH and Combined Impedance-pH Monitoring in Children
por: Shin, Myung Seok
Publicado: (2014)

Electrochemical Induced Calcium Phosphate Precipitation: Importance of Local pH
por: Lei, Yang, et al.
Publicado: (2017)

Textile-Based Potentiometric Electrochemical pH Sensor for Wearable Applications
por: Manjakkal, Libu, et al.
Publicado: (2019)

Thrombus formation is not pH-dependent
por: Weisshaar, Stefan, et al.
Publicado: (2010)

pH Dependence of Chitosan Enzymolysis
por: Gohi, Bi Foua Claude Alain, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_nb42is8r7499grtqgsaa3fds9p