Cargando…

Dual Nickel/Photoredox‐Catalyzed Site‐Selective Cross‐Coupling of 1,2‐Bis‐Boronic Esters Enabled by 1,2‐Boron Shifts

Site‐selective transition‐metal‐catalyzed mono‐deboronative cross‐couplings of 1,2‐bis‐boronic esters are valuable methods for the synthesis of functionalized organoboron compounds. However, such cross‐couplings are limited to reaction of the sterically less hindered primary boronic ester. Herein, w...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Hui, Han, Wangyujing, Noble, Adam, Aggarwal, Varinder K.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543306/ https://www.ncbi.nlm.nih.gov/pubmed/35779000 http://dx.doi.org/10.1002/anie.202207988

Ejemplares similares

Selective Coupling of 1,2‐Bis‐Boronic Esters at the more Substituted Site through Visible‐Light Activation of Electron Donor–Acceptor Complexes
por: Wang, Hui, et al.
Publicado: (2022)

Stereospecific 1,2‐Migrations of Boronate Complexes Induced by Electrophiles
por: Wang, Hui, et al.
Publicado: (2020)

Regio‐ and Stereoselective Homologation of 1,2‐Bis(Boronic Esters): Stereocontrolled Synthesis of 1,3‐Diols and Sch 725674
por: Fawcett, Alexander, et al.
Publicado: (2016)

Alkynyl Moiety for Triggering 1,2‐Metallate Shifts: Enantiospecific sp(2)–sp(3) Coupling of Boronic Esters with p‐Arylacetylenes
por: Ganesh, Venkataraman, et al.
Publicado: (2017)

Enantiospecific Synthesis of ortho-Substituted Benzylic Boronic Esters by a 1,2-Metalate Rearrangement/1,3-Borotropic Shift Sequence
por: Aichhorn, Stefan, et al.
Publicado: (2017)

Visible‐Light‐Mediated Decarboxylative Radical Additions to Vinyl Boronic Esters: Rapid Access to γ‐Amino Boronic Esters
por: Noble, Adam, et al.
Publicado: (2018)

Decarboxylation of β-boryl NHPI esters enables radical 1,2-boron shift for the assembly of versatile organoborons
por: Guo, Yu, et al.
Publicado: (2023)

Dual Ni/photoredox-catalyzed asymmetric cross-coupling to access chiral benzylic boronic esters
por: Zheng, Purui, et al.
Publicado: (2021)

Stereodivergent Olefination of Enantioenriched Boronic Esters
por: Armstrong, Roly J., et al.
Publicado: (2016)

Diastereodivergent Synthesis of Cyclopentyl Boronic Esters Bearing Contiguous Fully Substituted Stereocenters
por: Fairchild, Molly E., et al.
Publicado: (2022)

Enantiospecific Trifluoromethyl‐Radical‐Induced Three‐Component Coupling of Boronic Esters with Furans
por: Wang, Yahui, et al.
Publicado: (2017)

Enantiospecific sp(2)–sp(3) Coupling of ortho‐ and para‐Phenols with Secondary and Tertiary Boronic Esters
por: Wilson, Claire M., et al.
Publicado: (2017)

Synthesis of 1,3‐Bis‐(boryl)alkanes through Boronic Ester Induced Consecutive Double 1,2‐Migration
por: You, Cai, et al.
Publicado: (2020)

Chiral Aniline Synthesis via Stereospecific C(sp(3))–C(sp(2)) Coupling of Boronic Esters with Aryl Hydrazines
por: Ganesh, Venkataraman, et al.
Publicado: (2018)

Stereocontrolled Total Synthesis of Bastimolide B Using Iterative Homologation of Boronic Esters
por: Fiorito, Daniele, et al.
Publicado: (2022)

Three-component 1,2-carboamination of vinyl boronic esters via amidyl radical induced 1,2-migration
por: You, Cai, et al.
Publicado: (2021)

Allylboronic Esters as Acceptors in Radical Addition, Boron 1,2-Migration, and Trapping Cascades
por: Jana, Kalipada, et al.
Publicado: (2022)

A Lewis Base Catalysis Approach for the Photoredox Activation of Boronic Acids and Esters
por: Lima, Fabio, et al.
Publicado: (2017)

Iridium-Catalyzed Asymmetric Difunctionalization of C–C σ-Bonds Enabled by Ring-Strained Boronate Complexes
por: Shen, Hong-Cheng, et al.
Publicado: (2023)

Photoredox‐Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition–Polar Cyclization Cascade
por: Shu, Chao, et al.
Publicado: (2019)

Photoredox-catalyzed multicomponent Petasis reaction in batch and continuous flow with alkyl boronic acids
por: Oliva, Monica, et al.
Publicado: (2021)

Desymmetrization of C (2)‐Symmetric Bis(Boronic Esters) by Zweifel Olefinations
por: Linne, Yannick, et al.
Publicado: (2020)

Photoredox‐Mediated Deoxygenative Radical Additions of Aromatic Acids to Vinyl Boronic Esters and gem‐Diborylalkenes
por: Nagaraju, Anugula, et al.
Publicado: (2022)

Development of Enantiospecific Coupling of Secondary and Tertiary Boronic Esters with Aromatic Compounds
por: Odachowski, Marcin, et al.
Publicado: (2016)

Visible Light Activation of Boronic Esters Enables Efficient Photoredox C(sp(2))–C(sp(3)) Cross‐Couplings in Flow
por: Lima, Fabio, et al.
Publicado: (2016)

Synthesis and Functionalization of Tertiary Propargylic Boronic Esters by Alkynyllithium-Mediated 1,2-Metalate Rearrangement of Borylated Cyclopropanes
por: Pavlíčková, Tereza, et al.
Publicado: (2022)

Hypervalent iodine-mediated β-difluoroalkylboron synthesis via an unusual 1,2-hydrogen shift enabled by boron substitution
por: Lv, Wen-Xin, et al.
Publicado: (2022)

Radical‐Induced 1,2‐Migrations of Boron Ate Complexes
por: Kischkewitz, Marvin, et al.
Publicado: (2020)

Nickel-catalyzed enantioselective 1,2-vinylboration of styrenes
por: Ye, Yang, et al.
Publicado: (2021)

A Solid-State (11)B NMR and Computational Study of Boron Electric Field Gradient and Chemical Shift Tensors in Boronic Acids and Boronic Esters
por: Weiss, Joseph W. E., et al.
Publicado: (2010)

Atropo‐Enantioselective Oxidation‐Enabled Iridium(III)‐Catalyzed C−H Arylations with Aryl Boronic Esters
por: Woźniak, Łukasz, et al.
Publicado: (2021)

Metallacarborane Synthons for Molecular Construction—Oligofunctionalization of Cobalt Bis(1,2-dicarbollide) on Boron and Carbon Atoms with Extendable Ligands
por: Śmiałkowski, Krzysztof, et al.
Publicado: (2023)

Intramolecular Hydrogen Atom Transfer Induced 1,2-Migration of Boronate Complexes
por: Wang, Dinghai, et al.
Publicado: (2021)

Aluminum–Boron Bond Formation by Boron Ester Oxidative Addition at an Alumanyl Anion
por: Liu, Han-Ying, et al.
Publicado: (2023)

Radical boron migration of allylboronic esters
por: Tao, Xiangzhang, et al.
Publicado: (2022)

Photoredox catalysis in nickel-catalyzed C–H functionalization
por: Mantry, Lusina, et al.
Publicado: (2021)

Dual Nickel/Photoredox-Catalyzed Asymmetric Carbosulfonylation of Alkenes
por: Du, Xiaoyong, et al.
Publicado: (2023)

Nickel/photoredox dual catalyzed arylalkylation of nonactivated alkenes
por: Gao, Yuxi, et al.
Publicado: (2023)

Boron-catalyzed dehydrative allylation of 1,3-diketones and β-ketone esters with 1,3-diarylallyl alcohols in water
por: Zhang, Guo-Min, et al.
Publicado: (2021)

Bis(diethylenetriamine-κ(3) N,N′,N′′)nickel(II) bis(1,2-dicyanoethene-1,2-dithiolato-κ(2) S,S′)nickel(II)
por: Zhang, Dao-Peng, et al.
Publicado: (2008)

Cannot write session to /tmp/vufind_sessions/sess_s0ku1cf4irbc67ja9lr6sg6ich