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Metal–ligand Lability and Ligand Mobility Enables Framework Transformation via Ligand Release in a Family of Crystalline 2D Coordination Polymers

A family of seven silver(I)‐perfluorocarboxylate‐quinoxaline coordination polymers, [Ag(4)(O(2)CR(F))(4)(quin)(4)] 1–5 (R(F)=(CF(2))(n‐1)CF(3))(4), n=1 to 5); [Ag(4)(O(2)C(CF(2))(2)CO(2))(2)(quin)(4)] 6; [Ag(4)(O(2)CC(6)F(5))(4)(quin)(4)] 7 (quin=quinoxaline), denoted by composition as 4 : 4 : 4 pha...

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Detalles Bibliográficos
Autores principales: Lang, Feifan, Singh, Daljit C. N. G., Rao, Abhishek B., Romer, Catherine, Wright, James S., Smith, Rebecca, Adams, Harry, Brammer, Lee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543667/
https://www.ncbi.nlm.nih.gov/pubmed/35675317
http://dx.doi.org/10.1002/chem.202201408