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Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors
The valorization of alkenoic acids possibly deriving from biomass (fumaric and citraconic acids) was carried out through conversion in important building blocks, such as γ‐keto acids and succinic acid derivatives. The functionalization was carried out by addition onto the C=C double bond of radicals...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543820/ https://www.ncbi.nlm.nih.gov/pubmed/35695876 http://dx.doi.org/10.1002/cssc.202200898 |
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author | Jorea, Alexandra Ravelli, Davide Romarowski, Rodrigo M. Marconi, Stefania Auricchio, Ferdinando Fagnoni, Maurizio |
author_facet | Jorea, Alexandra Ravelli, Davide Romarowski, Rodrigo M. Marconi, Stefania Auricchio, Ferdinando Fagnoni, Maurizio |
author_sort | Jorea, Alexandra |
collection | PubMed |
description | The valorization of alkenoic acids possibly deriving from biomass (fumaric and citraconic acids) was carried out through conversion in important building blocks, such as γ‐keto acids and succinic acid derivatives. The functionalization was carried out by addition onto the C=C double bond of radicals generated under photocatalyzed conditions from suitable hydrogen donors (mainly aldehydes) and by adopting a decatungstate salt as the photocatalyst. Syntheses were performed under batch (in a glass vessel) and flow (by using 3D‐printed reactors) conditions. The design of the latter reactors allowed for an improved yield and productivity. |
format | Online Article Text |
id | pubmed-9543820 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-95438202022-10-14 Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors Jorea, Alexandra Ravelli, Davide Romarowski, Rodrigo M. Marconi, Stefania Auricchio, Ferdinando Fagnoni, Maurizio ChemSusChem Research Articles The valorization of alkenoic acids possibly deriving from biomass (fumaric and citraconic acids) was carried out through conversion in important building blocks, such as γ‐keto acids and succinic acid derivatives. The functionalization was carried out by addition onto the C=C double bond of radicals generated under photocatalyzed conditions from suitable hydrogen donors (mainly aldehydes) and by adopting a decatungstate salt as the photocatalyst. Syntheses were performed under batch (in a glass vessel) and flow (by using 3D‐printed reactors) conditions. The design of the latter reactors allowed for an improved yield and productivity. John Wiley and Sons Inc. 2022-07-08 2022-09-07 /pmc/articles/PMC9543820/ /pubmed/35695876 http://dx.doi.org/10.1002/cssc.202200898 Text en © 2022 The Authors. ChemSusChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Jorea, Alexandra Ravelli, Davide Romarowski, Rodrigo M. Marconi, Stefania Auricchio, Ferdinando Fagnoni, Maurizio Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title | Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title_full | Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title_fullStr | Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title_full_unstemmed | Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title_short | Photocatalyzed Functionalization of Alkenoic Acids in 3D‐Printed Reactors |
title_sort | photocatalyzed functionalization of alkenoic acids in 3d‐printed reactors |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9543820/ https://www.ncbi.nlm.nih.gov/pubmed/35695876 http://dx.doi.org/10.1002/cssc.202200898 |
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