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Solvent‐Dependent Oxidative Addition and Reductive Elimination of H(2) Across a Gallium‐Zinc Bond

H(2) adds reversibly across the metal‐metal bond of [(BDI)Ga(H)−Zn(tmeda)(thf)][BAr(4) (F)] (BDI=[HC{C(CH(3))N(2,6‐iPr(2)‐C(6)H(3))}(2)](−), TMEDA=N,N,N′,N′‐tetramethylethylenediamine, BAr(4) (F−)=[B(C(6)H(3)‐3,5‐(CF(3))(2))(4)](−)). Due to the stabilising effect of solvent coordination, hydrogenati...

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Detalles Bibliográficos
Autores principales:	Morris, Louis J., Rajeshkumar, Thayalan, Okumura, Akira, Maron, Laurent, Okuda, Jun
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544028/ https://www.ncbi.nlm.nih.gov/pubmed/35833688 http://dx.doi.org/10.1002/anie.202208855

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