Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene

The majority of binary chalcogen fluorides are fiercely reactive and extremely difficult to handle. Here, we show that access to crystalline donor‐acceptor complexes between chalcogen difluorides (sulfur, selenium) and tetrafluorides (selenium, tellurium) with the N‐heterocyclic carbene (NHC) 1,3‐bi...

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Autores principales: Komorr, Pascal, Olaru, Marian, Hupf, Emanuel, Mebs, Stefan, Beckmann, Jens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544779/
https://www.ncbi.nlm.nih.gov/pubmed/35587690
http://dx.doi.org/10.1002/chem.202201023
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author Komorr, Pascal
Olaru, Marian
Hupf, Emanuel
Mebs, Stefan
Beckmann, Jens
author_facet Komorr, Pascal
Olaru, Marian
Hupf, Emanuel
Mebs, Stefan
Beckmann, Jens
author_sort Komorr, Pascal
collection PubMed
description The majority of binary chalcogen fluorides are fiercely reactive and extremely difficult to handle. Here, we show that access to crystalline donor‐acceptor complexes between chalcogen difluorides (sulfur, selenium) and tetrafluorides (selenium, tellurium) with the N‐heterocyclic carbene (NHC) 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene (IPr) is possible conveniently and safely without the need to generate the highly unstable EF(2) (E=S, Se) or the very toxic and corrosive SeF(4).
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spelling pubmed-95447792022-10-14 Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene Komorr, Pascal Olaru, Marian Hupf, Emanuel Mebs, Stefan Beckmann, Jens Chemistry Research Articles The majority of binary chalcogen fluorides are fiercely reactive and extremely difficult to handle. Here, we show that access to crystalline donor‐acceptor complexes between chalcogen difluorides (sulfur, selenium) and tetrafluorides (selenium, tellurium) with the N‐heterocyclic carbene (NHC) 1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene (IPr) is possible conveniently and safely without the need to generate the highly unstable EF(2) (E=S, Se) or the very toxic and corrosive SeF(4). John Wiley and Sons Inc. 2022-06-20 2022-08-10 /pmc/articles/PMC9544779/ /pubmed/35587690 http://dx.doi.org/10.1002/chem.202201023 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Komorr, Pascal
Olaru, Marian
Hupf, Emanuel
Mebs, Stefan
Beckmann, Jens
Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title_full Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title_fullStr Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title_full_unstemmed Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title_short Donor Acceptor Complexes between the Chalcogen Fluorides SF(2), SeF(2), SeF(4) and TeF(4) and an N‐Heterocyclic Carbene
title_sort donor acceptor complexes between the chalcogen fluorides sf(2), sef(2), sef(4) and tef(4) and an n‐heterocyclic carbene
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9544779/
https://www.ncbi.nlm.nih.gov/pubmed/35587690
http://dx.doi.org/10.1002/chem.202201023
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