CO(2) Separation by Imide/Imine Organic Cages

Two novel imide/imine‐based organic cages have been prepared and studied as materials for the selective separation of CO(2) from N(2) and CH(4) under vacuum swing adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO(2) over N(2) and CH(4). The cages were also tested a...

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Autores principales: La Cognata, Sonia, Mobili, Riccardo, Milanese, Chiara, Boiocchi, Massimo, Gaboardi, Mattia, Armentano, Donatella, Jansen, Johannes C., Monteleone, Marcello, Antonangelo, Ariana R., Carta, Mariolino, Amendola, Valeria
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545214/
https://www.ncbi.nlm.nih.gov/pubmed/35762229
http://dx.doi.org/10.1002/chem.202201631
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author La Cognata, Sonia
Mobili, Riccardo
Milanese, Chiara
Boiocchi, Massimo
Gaboardi, Mattia
Armentano, Donatella
Jansen, Johannes C.
Monteleone, Marcello
Antonangelo, Ariana R.
Carta, Mariolino
Amendola, Valeria
author_facet La Cognata, Sonia
Mobili, Riccardo
Milanese, Chiara
Boiocchi, Massimo
Gaboardi, Mattia
Armentano, Donatella
Jansen, Johannes C.
Monteleone, Marcello
Antonangelo, Ariana R.
Carta, Mariolino
Amendola, Valeria
author_sort La Cognata, Sonia
collection PubMed
description Two novel imide/imine‐based organic cages have been prepared and studied as materials for the selective separation of CO(2) from N(2) and CH(4) under vacuum swing adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO(2) over N(2) and CH(4). The cages were also tested as fillers in mixed‐matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid® or PEEK‐WC polymers. Improved gas‐transport properties and selectivity for CO(2) were achieved compared to the neat polymer membranes.
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spelling pubmed-95452142022-10-14 CO(2) Separation by Imide/Imine Organic Cages La Cognata, Sonia Mobili, Riccardo Milanese, Chiara Boiocchi, Massimo Gaboardi, Mattia Armentano, Donatella Jansen, Johannes C. Monteleone, Marcello Antonangelo, Ariana R. Carta, Mariolino Amendola, Valeria Chemistry Research Articles Two novel imide/imine‐based organic cages have been prepared and studied as materials for the selective separation of CO(2) from N(2) and CH(4) under vacuum swing adsorption conditions. Gas adsorption on the new compounds showed selectivity for CO(2) over N(2) and CH(4). The cages were also tested as fillers in mixed‐matrix membranes for gas separation. Dense and robust membranes were obtained by loading the cages in either Matrimid® or PEEK‐WC polymers. Improved gas‐transport properties and selectivity for CO(2) were achieved compared to the neat polymer membranes. John Wiley and Sons Inc. 2022-07-25 2022-09-01 /pmc/articles/PMC9545214/ /pubmed/35762229 http://dx.doi.org/10.1002/chem.202201631 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
La Cognata, Sonia
Mobili, Riccardo
Milanese, Chiara
Boiocchi, Massimo
Gaboardi, Mattia
Armentano, Donatella
Jansen, Johannes C.
Monteleone, Marcello
Antonangelo, Ariana R.
Carta, Mariolino
Amendola, Valeria
CO(2) Separation by Imide/Imine Organic Cages
title CO(2) Separation by Imide/Imine Organic Cages
title_full CO(2) Separation by Imide/Imine Organic Cages
title_fullStr CO(2) Separation by Imide/Imine Organic Cages
title_full_unstemmed CO(2) Separation by Imide/Imine Organic Cages
title_short CO(2) Separation by Imide/Imine Organic Cages
title_sort co(2) separation by imide/imine organic cages
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545214/
https://www.ncbi.nlm.nih.gov/pubmed/35762229
http://dx.doi.org/10.1002/chem.202201631
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