Cargando…
Dynamic Stereochemistry of a Biphenyl‐Bisprolineamide Model Catalyst and its Imidazolidinone Intermediates
In this study, we characterize the dynamic stereochemistry of a biphenyl‐2,2’‐bis(proline amide) catalyst in chloroform and DMSO as representative weakly and strongly hydrogen bonding solvents. Using vibrational circular dichroism (VCD) spectroscopy and density functional theory (DFT) based spectra...
Autores principales: | Golub, Tino P., Feßner, Malte, Engelage, Elric, Merten, Christian |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9545261/ https://www.ncbi.nlm.nih.gov/pubmed/35611719 http://dx.doi.org/10.1002/chem.202201317 |
Ejemplares similares
-
Stereochemistry Controls Dihydrogen Bonding Strengths in Chiral Amine Boranes Adducts
por: Kemper, Michael, et al.
Publicado: (2022) -
Stereochemistry of the Reaction Intermediates of Prolinol Ether Catalyzed Reactions Characterized by Vibrational Circular Dichroism Spectroscopy
por: Golub, Tino P., et al.
Publicado: (2020) -
Chiral Molecular Propellers of Triarylborane Ammonia Adducts
por: Kemper, Michael, et al.
Publicado: (2020) -
Inducing Propeller Chirality in Triaryl Boranes with Chiral Amines
por: Kemper, Michael, et al.
Publicado: (2022) -
Synthesis of Polycyclic Imidazolidinones via Amine
Redox-Annulation
por: Zhu, Zhengbo, et al.
Publicado: (2017)