Cargando…

In Situ Grignard Metalation Method for the Synthesis of Hauser Bases

The in situ Grignard Metalation Method (iGMM) is a straightforward one‐pot procedure to quickly produce multigram amounts of Hauser bases R(2)N‐MgBr which are valuable and vastly used metalation reagents and novel electrolytes for magnesium batteries. During addition of bromoethane to a suspension o...

Descripción completa

Detalles Bibliográficos
Autores principales:	Sengupta, Simon, Schüler, Philipp, Görls, Helmar, Liebing, Phil, Krieck, Sven, Westerhausen, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546396/ https://www.ncbi.nlm.nih.gov/pubmed/35686618 http://dx.doi.org/10.1002/chem.202201359

Ejemplares similares

In situ Grignard Metalation Method, Part II: Scope of the One‐Pot Synthesis of Organocalcium Compounds
por: Schüler, Philipp, et al.
Publicado: (2022)

One‐Step Synthesis and Schlenk‐Type Equilibrium of Cyclopentadienylmagnesium Bromides
por: Schüler, Philipp, et al.
Publicado: (2021)

Scope and Limitations of the s‐Block Metal‐Mediated Pudovik Reaction
por: Fener, Benjamin E., et al.
Publicado: (2020)

Bis(2,4,6-trimethylphenyl)zinc(II)
por: Krieck, Sven, et al.
Publicado: (2009)

Synthesis and Oligonuclear Structures of Strontium and Barium Complexes with Protonated and Deprotonated N-Mesityl-P,P-diphenylphosphinic Amide Ligands
por: Schönherr, Paul R. W., et al.
Publicado: (2021)

Disposable cartridge concept for the on-demand synthesis of turbo Grignards, Knochel–Hauser amides, and magnesium alkoxides
por: Berton, Mateo, et al.
Publicado: (2020)

2-(Benzoylaminomethyl)pyridinium chloride
por: Koch, Christian, et al.
Publicado: (2008)

A hydrogen-bridged adduct 3,4,6,7,8,9-hexahydro-2H-pyrimido[1,2-a]pyrimidin-1-ium [1,3-bis(tert-butyldimethylsilyloxy)-1,3-bis(pyridin-2-yl)propan-2-ylidene]nitronate acetonitrile monosolvate
por: Schulz, Martin, et al.
Publicado: (2011)

Bis[(2-pyridylmethyl)(triisopropylsilyl)amido]zinc(II)–toluene–tetrahydrofuran (4/2/1)
por: Koch, Christian, et al.
Publicado: (2008)

Bis(N-triisopropylsilylquinolin-8-aminato)nickel(II)
por: Malassa, Astrid, et al.
Publicado: (2009)

1-Nitro-2,3-di-2-pyridyl-2,3-dihydroindolizine
por: Schulz, Martin, et al.
Publicado: (2009)

Bis[μ-N-(tert-butyldimethylsilyl)-N-(pyridin-2-ylmethyl)amido]bis[methylcobalt(II)]
por: Malassa, Astrid, et al.
Publicado: (2012)

[1-Methoxy-3-(pyridin-2-yl)indolizin-2-yl](pyridin-2-yl)methanone
por: Kloubert, Tobias, et al.
Publicado: (2012)

Structure–Solubility Relationship of 1,4‐Dioxane Complexes of Di(hydrocarbyl)magnesium
por: Fischer, Reinald, et al.
Publicado: (2019)

Addition of CFCl(3) to Aromatic Aldehydes via in Situ Grignard Reaction
por: Barkakaty, Balaka, et al.
Publicado: (2015)

Synthesis of Bis-heteroaryls Using Grignard Reagents and Pyridylsulfonium Salts
por: Horan, Alexandra M., et al.
Publicado: (2021)

Synthesis of Mixed Arylalkyl Tertiary Phosphines via the Grignard Approach
por: Haque, Ashanul, et al.
Publicado: (2022)

Metal‐Bonded Redox‐Active Triarylamines and Their Interactions: Synthesis, Structure, and Redox Properties of Paddle‐Wheel Copper Complexes
por: Akintola, Oluseun, et al.
Publicado: (2019)

Metal‐Bonded Redox‐Active Triarylamines and Their Interactions: Synthesis, Structure, and Redox Properties of Paddle‐Wheel Copper Complexes
por: Akintola, Oluseun, et al.
Publicado: (2019)

Copper‐Catalyzed Addition of Grignard Reagents to in situ Generated Indole‐Derived Vinylogous Imines
por: Ge, Luo, et al.
Publicado: (2020)

Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes
por: Kessler, Simon N., et al.
Publicado: (2016)

Tertiary amine synthesis via reductive coupling of amides with Grignard reagents
por: Xie, Lan-Gui, et al.
Publicado: (2017)

Unusual Nucleophilic Addition of Grignard Reagents in the Synthesis of 4-Amino-pyrimidines
por: Tinson, Ryan A. J., et al.
Publicado: (2018)

Total Synthesis of Penicyclone A Using a Double Grignard Reaction
por: Talajić, Gregor, et al.
Publicado: (2022)

Front Cover: Metal‐Bonded Redox‐Active Triarylamines and Their Interactions: Synthesis, Structure, and Redox Properties of Paddle‐Wheel Copper Complexes (ChemistryOpen 3/2019)
por: Akintola, Oluseun, et al.
Publicado: (2019)

Standardization and Control of Grignard Reactions in a Universal Chemical Synthesis Machine using online NMR
por: Bornemann‐Pfeiffer, Martin, et al.
Publicado: (2021)

Iron-Catalyzed Cross-Coupling of α-Allenyl Esters with Grignard Reagents for the Synthesis of 1,3-Dienes
por: Kong, Wei-Jun, et al.
Publicado: (2023)

Kumada–Grignard-type biaryl couplings on water
por: Bhattacharjya, Anish, et al.
Publicado: (2015)

Grignard coupling-based synthesis of vinyl-substituted hydridopolycarbosilane: effect of starting material and polymerization behavior
por: Jeong, Minji, et al.
Publicado: (2021)

Very short highly enantioselective Grignard synthesis of 2,2-disubstituted tetrahydrofurans and tetrahydropyrans
por: Monasterolo, Claudio, et al.
Publicado: (2019)

Synthesis of 1,2,3-triazoles using Grignard reactions through the protection of azides
por: Namioka, Rina, et al.
Publicado: (2023)

Chemoselective Nozaki–Hiyama–Takai–Kishi and Grignard reaction: short synthesis of some carbahexopyranoses
por: Vinaykumar, Allam, et al.
Publicado: (2023)

Pyrrolic and Dipyrrolic Chlorophyll Degradation Products in Plants and Herbivores
por: Ritter, Marcel, et al.
Publicado: (2020)

A Synthesis of Substituted α-Allenols via Iron-Catalyzed Cross-Coupling of Propargyl Carboxylates with Grignard Reagents
por: Kessler, Simon N., et al.
Publicado: (2016)

Gayelord hauser' s treasury of secrets
por: Hauser, Gayelord
Publicado: (1963)

Investigation of Grignard Reagent as an Advanced Base for Aza-Claisen Rearrangement
por: Song, Bo Reum, et al.
Publicado: (2019)

Synthesis and structural characterization of four dichloridobis(cyclopropylalkynylamidine)metal complexes
por: Wang, Sida, et al.
Publicado: (2018)

Empowering alcohols as carbonyl surrogates for Grignard-type reactions
por: Li, Chen-Chen, et al.
Publicado: (2020)

Pd-catalyzed allylative dearomatisation using Grignard reagents
por: Boldrini, Cosimo, et al.
Publicado: (2021)

Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines
por: Han, Hyun Ji, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_b10bt32iod4bcj4c3dis9otamb