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Revealing the Role of the Cyaphide Ion as a Bridging Ligand in Heterometallic Complexes

The synthesis of heterometallic transition metal complexes featuring bridging cyaphide ions (C≡P(−)) is reported. These are synthesized from reactions of Au(IDipp)(CP) (IDipp=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene) with electron‐rich, nucleophilic transition metal reagents, affording Au(ID...

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Detalles Bibliográficos
Autores principales: Yang, Eric S., Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9546431/
https://www.ncbi.nlm.nih.gov/pubmed/35695304
http://dx.doi.org/10.1002/anie.202206783

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