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Unimolecular Kinetics of Stabilized CH(3)CHOO Criegee Intermediates: syn-CH(3)CHOO Decomposition and anti-CH(3)CHOO Isomerization

[Image: see text] The kinetics of the unimolecular decomposition of the stabilized Criegee intermediate syn-CH(3)CHOO has been investigated at temperatures between 297 and 331 K and pressures between 12 and 300 Torr using laser flash photolysis of CH(3)CHI(2)/O(2)/N(2) gas mixtures coupled with time...

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Detalles Bibliográficos
Autores principales:	Robinson, Callum, Onel, Lavinia, Newman, James, Lade, Rachel, Au, Kendrew, Sheps, Leonid, Heard, Dwayne E., Seakins, Paul W., Blitz, Mark A., Stone, Daniel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9549458/ https://www.ncbi.nlm.nih.gov/pubmed/36146923 http://dx.doi.org/10.1021/acs.jpca.2c05461

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