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PIFA-mediated selenylative spirocyclization of indolyl ynones: facile access to selenated spiro[cyclopentenone-1,3′-indoles]

A fast selenylative spirocyclization of indolyl ynones mediated by PIFA has been developed. This transformation was enabled by the reactive RSeOCOCF(3) species generated in situ from diselenides with PIFA, involving an electrophilic dearomative cascade cyclization. This protocol provides a facile an...

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Detalles Bibliográficos
Autores principales:	Chen, Zhichao, Li, Jingjing, Weng, Wenting, Xie, Xiaolan, Lei, Jian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9549584/ https://www.ncbi.nlm.nih.gov/pubmed/36320507 http://dx.doi.org/10.1039/d2ra05387j

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