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Stereodivergent dehydrative allylation of β-keto esters using a Ru/Pd synergistic catalyst

α-Alkylation of a β-keto ester is a frequently used reaction for carbon–carbon bond formation. However, extension to a stereoselective reaction remains a significant challenge, because the product easily racemizes under acidic or basic conditions. Here, we report a hybrid system consisting of Pd and...

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Detalles Bibliográficos
Autores principales: Le, Thien Phuc, Tanaka, Shinji, Yoshimura, Masahiro, Sato, Kazuhiko, Kitamura, Masato
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9556617/
https://www.ncbi.nlm.nih.gov/pubmed/36224190
http://dx.doi.org/10.1038/s41467-022-33432-4