Influence of the anionic structure and central atom of a cation on the properties of LCST-type draw solutes for forward osmosis

Thermo-responsive ionic compounds were synthesized to examine if they have a powerful ability to draw solutes for forward osmosis (FO). The investigated compounds were tetrabutylammonium benzenesulfonate, tetrabutylphosphonium benzenesulfonate, tetrabutylammonium 2-naphthalenesulfonate, and tetrabutylphosphonium 2-naphthalenesulfonate (abbreviated as [N(4444)][BS], [P(4444)][BS], [N(4444)][NS], and [P(4444)][NS]). The lower critical solution temperature (LCST) characteristics of the materials that formed the monocyclic aromatic compound [BS] were not confirmed; however, the LCSTs of others that formed the bicyclic aromatic compound [NS] were confirmed to be approximately 37 °C ([N(4444)][NS]) and 19 °C ([P(4444)][NS]) at 20 wt% in aqueous solutions; this is valued in reducing the energy required for recovery of the draw solute. In addition, it suggests that ammonium-based ionic compounds have a higher recovery temperature than phosphonium-based ionic compounds. When an active layer was oriented to a draw solution (AL-DS mode) and using 20 wt% aqueous [N(4444)][NS] draw solution at room temperature, water and reverse solute fluxes were about 3.07 LMH and 0.58 gMH, respectively. Thus, this is the first study to investigate structural transformations of the anion and central atom of the cation and to examine prospective draw solutes of the FO system in this series.