One-Step Hydrothermal Synthesis, Thermochromic and Infrared Camouflage Properties of Vanadium Dioxide Nanorods

Vanadium dioxide (VO(2)) has attracted interest from researchers because it undergoes a metal–insulator phase transition (MIT), which is accompanied by a reversible and remarkable change in both electrical and optical properties. VO(2) exhibits numerous polymorphs and thus it is essential to control the growth of specific monoclinic VO(2) (M) and rutile VO(2) (R) phases. In this study, we developed a cost-effective and facile method for preparing VO(2) nanorods with a highly crystalline monoclinic phase by one-step hydrothermal synthesis, in which only V(2)O(5) and H(2)C(2)O(4) are used as raw materials. The phase evolution of VO(2) during the hydrothermal process was studied. The obtained VO(2) nanorods were thoroughly mixed with fluorocarbon resin and homogeneous emulsifier in an ethanol solution to obtain a VO(2) dispersion. To prepare VO(2) films, screen printing was performed with a stainless steel screen mesh mask on glasses or fabric substrate. The VO(2) coating had good thermochromic performance; the infrared transmittance change was greater than 20% @1.5 μm whilst keeping the visible transmittance greater than 50%. Meanwhile, the polyester base coating on the fabric had an emissivity change of up to 22%, which provides a solution for adaptive IR camouflage.