Cargando…
Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate
Modification of aluminosilicate minerals using a R(4)N(+)-bearing organic modifier, through the formation of covalent bonds, is an applicable way to eliminate the modifier release and to maintain the ability to remove cationic pollutants. In this study, trimethyl [3-(trimethoxysilyl) propyl] ammoniu...
Autores principales: | , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9566248/ https://www.ncbi.nlm.nih.gov/pubmed/36231863 http://dx.doi.org/10.3390/ijerph191912562 |
_version_ | 1784809104486694912 |
---|---|
author | Peng, Wang Cui, Zhanpeng Fu, Hongyan Cao, Hongkai Chen, Ming Zhang, Dachao Luo, Wuhui Ren, Sili |
author_facet | Peng, Wang Cui, Zhanpeng Fu, Hongyan Cao, Hongkai Chen, Ming Zhang, Dachao Luo, Wuhui Ren, Sili |
author_sort | Peng, Wang |
collection | PubMed |
description | Modification of aluminosilicate minerals using a R(4)N(+)-bearing organic modifier, through the formation of covalent bonds, is an applicable way to eliminate the modifier release and to maintain the ability to remove cationic pollutants. In this study, trimethyl [3-(trimethoxysilyl) propyl] ammonium chloride (TM) and/or dimethyl octadecyl [3-(trimethoxysilyl) propyl] ammonium chloride (DMO) were used to graft three aluminosilicate minerals, including calcined kaolinite (Kaol), montmorillonite (Mt), and zeolite (Zeol), and the obtained composites were deployed to assess their performance in regard to ammonium (NH(4)(+)) and nitrate (NO(3)(−)) adsorption. Grafting of TM and/or DMO had little influence on the crystal structures of Kaol and Zeol, but it increased the interlayer distance of Mt due to the intercalation. Compared to Kaol and Zeol, Mt had a substantially greater grafting concentration of organosilane. For Mt, the highest amount of loaded organosilane was observed when TM and DMO were used simultaneously, whereas for Kaol and Zeol, this occurred when only DMO was employed. (29)Si-NMR spectra revealed that TM and/or DMO were covalently bonded on Mt. As opposed to NO(3)(−), the amount of adsorbed NH(4)(+) was reduced after TM and/or DMO grafting while having little effect on the adsorption rate. For the grafted Kaol and Zeol, the adsorption of NH(4)(+) and NO(3)(−) was non-interfering. This is different from the grafted Mt where NH(4)(+) uptake was aided by the presence of NO(3)(−). The higher concentration of DMO accounted for the larger NO(3)(−) uptake, which was accompanied by improved affinity. The results provide a reference for grafting aluminosilicate minerals and designing efficient adsorbents for the co-adsorption of NH(4)(+) and NO(3)(−). |
format | Online Article Text |
id | pubmed-9566248 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-95662482022-10-15 Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate Peng, Wang Cui, Zhanpeng Fu, Hongyan Cao, Hongkai Chen, Ming Zhang, Dachao Luo, Wuhui Ren, Sili Int J Environ Res Public Health Article Modification of aluminosilicate minerals using a R(4)N(+)-bearing organic modifier, through the formation of covalent bonds, is an applicable way to eliminate the modifier release and to maintain the ability to remove cationic pollutants. In this study, trimethyl [3-(trimethoxysilyl) propyl] ammonium chloride (TM) and/or dimethyl octadecyl [3-(trimethoxysilyl) propyl] ammonium chloride (DMO) were used to graft three aluminosilicate minerals, including calcined kaolinite (Kaol), montmorillonite (Mt), and zeolite (Zeol), and the obtained composites were deployed to assess their performance in regard to ammonium (NH(4)(+)) and nitrate (NO(3)(−)) adsorption. Grafting of TM and/or DMO had little influence on the crystal structures of Kaol and Zeol, but it increased the interlayer distance of Mt due to the intercalation. Compared to Kaol and Zeol, Mt had a substantially greater grafting concentration of organosilane. For Mt, the highest amount of loaded organosilane was observed when TM and DMO were used simultaneously, whereas for Kaol and Zeol, this occurred when only DMO was employed. (29)Si-NMR spectra revealed that TM and/or DMO were covalently bonded on Mt. As opposed to NO(3)(−), the amount of adsorbed NH(4)(+) was reduced after TM and/or DMO grafting while having little effect on the adsorption rate. For the grafted Kaol and Zeol, the adsorption of NH(4)(+) and NO(3)(−) was non-interfering. This is different from the grafted Mt where NH(4)(+) uptake was aided by the presence of NO(3)(−). The higher concentration of DMO accounted for the larger NO(3)(−) uptake, which was accompanied by improved affinity. The results provide a reference for grafting aluminosilicate minerals and designing efficient adsorbents for the co-adsorption of NH(4)(+) and NO(3)(−). MDPI 2022-10-01 /pmc/articles/PMC9566248/ /pubmed/36231863 http://dx.doi.org/10.3390/ijerph191912562 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Peng, Wang Cui, Zhanpeng Fu, Hongyan Cao, Hongkai Chen, Ming Zhang, Dachao Luo, Wuhui Ren, Sili Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title | Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title_full | Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title_fullStr | Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title_full_unstemmed | Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title_short | Grafting of R(4)N(+)-Bearing Organosilane on Kaolinite, Montmorillonite, and Zeolite for Simultaneous Adsorption of Ammonium and Nitrate |
title_sort | grafting of r(4)n(+)-bearing organosilane on kaolinite, montmorillonite, and zeolite for simultaneous adsorption of ammonium and nitrate |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9566248/ https://www.ncbi.nlm.nih.gov/pubmed/36231863 http://dx.doi.org/10.3390/ijerph191912562 |
work_keys_str_mv | AT pengwang graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT cuizhanpeng graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT fuhongyan graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT caohongkai graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT chenming graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT zhangdachao graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT luowuhui graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate AT rensili graftingofr4nbearingorganosilaneonkaolinitemontmorilloniteandzeoliteforsimultaneousadsorptionofammoniumandnitrate |