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Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal(2)323)](2)[ReCl(6)] (Hal = Cl, Br)
The cationic complexes of Mn(III) with the 5-Hal-sal(2)323 (Hal = Cl, Br) ligands and a paramagnetic doubly charged counterion [ReCl(6)](2−) have been synthesized: [Mn(5-Cl-sal(2)323)](2)[ReCl(6)] (1) and [Mn(5-Br-sal(2)323)](2)[ReCl(6)] (2). Their crystal structures and magnetic properties have bee...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9570138/ https://www.ncbi.nlm.nih.gov/pubmed/36232753 http://dx.doi.org/10.3390/ijms231911449 |