Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal(2)323)](2)[ReCl(6)] (Hal = Cl, Br)

The cationic complexes of Mn(III) with the 5-Hal-sal(2)323 (Hal = Cl, Br) ligands and a paramagnetic doubly charged counterion [ReCl(6)](2−) have been synthesized: [Mn(5-Cl-sal(2)323)](2)[ReCl(6)] (1) and [Mn(5-Br-sal(2)323)](2)[ReCl(6)] (2). Their crystal structures and magnetic properties have bee...

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Detalles Bibliográficos
Autores principales: Tiunova, Aleksandra V., Kazakova, Anna V., Korchagin, Denis V., Shilov, Gennady V., Aldoshin, Sergey M., Dmitriev, Aleksei I., Zhidkov, Mikhail V., Zakharov, Konstantin V., Yagubskii, Eduard B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9570138/
https://www.ncbi.nlm.nih.gov/pubmed/36232753
http://dx.doi.org/10.3390/ijms231911449

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