Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides

Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)(2) catal...

Descripción completa

Detalles Bibliográficos
Autores principales: Yu, Xin-Zhang, Wei, Wen-Long, Niu, Yu-Lan, Li, Xing, Wang, Ming, Gao, Wen-Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571168/
https://www.ncbi.nlm.nih.gov/pubmed/36234770
http://dx.doi.org/10.3390/molecules27196232
_version_ 1784810295067148288
author Yu, Xin-Zhang
Wei, Wen-Long
Niu, Yu-Lan
Li, Xing
Wang, Ming
Gao, Wen-Chao
author_facet Yu, Xin-Zhang
Wei, Wen-Long
Niu, Yu-Lan
Li, Xing
Wang, Ming
Gao, Wen-Chao
author_sort Yu, Xin-Zhang
collection PubMed
description Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)(2) catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system.
format Online
Article
Text
id pubmed-9571168
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-95711682022-10-17 Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides Yu, Xin-Zhang Wei, Wen-Long Niu, Yu-Lan Li, Xing Wang, Ming Gao, Wen-Chao Molecules Article Symmetrical diaryl sulfides and diaryl disulfides have been efficiently and selectively constructed via the homocoupling of sodium arenesulfinates. The selectivity of products relied on the different reaction systems: symmetrical diaryl sulfides were predominately obtained under the Pd(OAc)(2) catalysis, whereas symmetrical diaryl sulfides were exclusively yielded in the presence of the reductive Fe/HCl system. MDPI 2022-09-22 /pmc/articles/PMC9571168/ /pubmed/36234770 http://dx.doi.org/10.3390/molecules27196232 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yu, Xin-Zhang
Wei, Wen-Long
Niu, Yu-Lan
Li, Xing
Wang, Ming
Gao, Wen-Chao
Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title_full Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title_fullStr Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title_full_unstemmed Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title_short Homocouplings of Sodium Arenesulfinates: Selective Access to Symmetric Diaryl Sulfides and Diaryl Disulfides
title_sort homocouplings of sodium arenesulfinates: selective access to symmetric diaryl sulfides and diaryl disulfides
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571168/
https://www.ncbi.nlm.nih.gov/pubmed/36234770
http://dx.doi.org/10.3390/molecules27196232
work_keys_str_mv AT yuxinzhang homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides
AT weiwenlong homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides
AT niuyulan homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides
AT lixing homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides
AT wangming homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides
AT gaowenchao homocouplingsofsodiumarenesulfinatesselectiveaccesstosymmetricdiarylsulfidesanddiaryldisulfides

Ejemplares similares