Cargando…

Silver Catalyzed Site-Selective C(sp(3))−H Bond Amination of Secondary over Primary C(sp(3))−H Bonds

Sulfamates are widespread in numerous pharmacologically active molecules. In this paper, Silver/Bathophenanthroline catalyzed the intramolecular selective amination of primary C(sp(3))−H bonds and secondary C(sp(3))−H bonds of sulfamate esters, to produce cyclic sulfamates in good yields and with a...

Descripción completa

Detalles Bibliográficos
Autores principales:	Jiao, Luzhen, Teng, Dawei, Wang, Zixuan, Cao, Guorui
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2022
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571442/ https://www.ncbi.nlm.nih.gov/pubmed/36234711 http://dx.doi.org/10.3390/molecules27196174

Ejemplares similares

Synthesis of (diarylmethyl)amines using Ni-catalyzed arylation of C(sp(3))–H bonds
por: Fernández-Salas, José A., et al.
Publicado: (2015)

Photo-induced copper-catalyzed alkynylation and amination of remote unactivated C(sp(3))-H bonds
por: Cao, Zhusong, et al.
Publicado: (2021)

Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
por: Barsu, Nagaraju, et al.
Publicado: (2017)

Practical Catalytic Cleavage of C(sp(3))−C(sp(3)) Bonds in Amines
por: Li, Wu, et al.
Publicado: (2019)

Modular synthesis of dihydro-isoquinolines: palladium-catalyzed sequential C(sp(2))–H and C(sp(3))–H bond activation
por: Liu, Weidong, et al.
Publicado: (2015)

Ligand-Promoted Alkylation of C(sp(3))–H and C(sp(2))–H Bonds
por: Zhu, Ru-Yi, et al.
Publicado: (2014)

Transition‐Metal‐Catalyzed Annulations Involving the Activation of C(sp(3))−H Bonds
por: Font, Marc, et al.
Publicado: (2021)

Ni-catalyzed benzylic β-C(sp(3))–H bond activation of formamides
por: Wang, Rong-Hua, et al.
Publicado: (2022)

Mechanism and Selectivity of Copper-Catalyzed Bromination of Distal C(sp(3))–H Bonds
por: Ajitha, Manjaly J., et al.
Publicado: (2023)

Visible-light promoted regioselective amination and alkylation of remote C(sp(3))-H bonds
por: Guo, Quanping, et al.
Publicado: (2020)

Recent developments for intermolecular enantioselective amination of non-acidic C(sp(3))–H bonds
por: Li, Heng-Hui, et al.
Publicado: (2023)

Effect of α-Substitution on the Reactivity of C(sp(3))–H Bonds in Pd(0)-Catalyzed C–H Arylation
por: Wheatley, Matthew, et al.
Publicado: (2023)

Diverse secondary C(sp(3))–H bond functionalization via site-selective trifluoroacetoxylation of aliphatic amines
por: Tang, Yongzhen, et al.
Publicado: (2018)

Dithiane-directed Rh(iii)-catalyzed amidation of unactivated C(sp(3))–H bonds
por: Shi, Heyao, et al.
Publicado: (2019)

Photoredox-catalyzed C–C bond cleavage of cyclopropanes for the formation of C(sp(3))–heteroatom bonds
por: Ge, Liang, et al.
Publicado: (2022)

Site-selective bromination of sp(3) C–H bonds
por: Sathyamoorthi, Shyam, et al.
Publicado: (2017)

Enantioselective carbenoid insertion into C(sp(3))–H bonds
por: Santiago, J V, et al.
Publicado: (2016)

Bi-Catalyzed Trifluoromethylation of C(sp(2))–H Bonds under Light
por: Tsuruta, Takuya, et al.
Publicado: (2023)

An iron(ii)-based metalloradical system for intramolecular amination of C(sp(2))–H and C(sp(3))–H bonds: synthetic applications and mechanistic studies
por: Das, Sandip Kumar, et al.
Publicado: (2022)

Ritter-type amination of C(sp(3))-H bonds enabled by electrochemistry with SO(4)(2−)
por: Zhang, Ling, et al.
Publicado: (2022)

Cobalt catalyzed sp(3) C–H amination utilizing aryl azides
por: Villanueva, Omar, et al.
Publicado: (2015)

Recent advances in Cu-catalyzed C(sp(3))–Si and C(sp(3))–B bond formation
por: Takale, Balaram S, et al.
Publicado: (2020)

Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp(3))–H bonds of aliphatic amine substrates
por: Wang, Chao, et al.
Publicado: (2015)

Cobalt-catalyzed nucleophilic addition of the allylic C(sp(3))–H bond of simple alkenes to ketones
por: Mita, Tsuyoshi, et al.
Publicado: (2018)

Copper-catalyzed intermolecular C(sp(3))–H bond functionalization towards the synthesis of tertiary carbamates
por: Chikkade, Prasanna Kumara, et al.
Publicado: (2015)

Multicomponent double Mannich alkylamination involving C(sp(2))–H and benzylic C(sp(3))–H bonds
por: Lai, Zhencheng, et al.
Publicado: (2022)

C(sp(3))−C(sp(3)) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
por: Cao, Dawei, et al.
Publicado: (2021)

Cobalt-Catalyzed, Aminoquinoline-Directed Coupling of sp(2) C–H Bonds with Alkenes
por: Grigorjeva, Liene, et al.
Publicado: (2014)

Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp(2))−H bonds
por: Qi, Shao-Long, et al.
Publicado: (2022)

From Isocyanides to Iminonitriles via Silver-mediated Sequential Insertion of C(sp(3))–H Bond
por: Chi, Huiwen, et al.
Publicado: (2019)

Photocatalytic Alkylation of C(sp(3))−H Bonds Using Sulfonylhydrazones
por: Pulcinella, Antonio, et al.
Publicado: (2022)

Intramolecular cascade annulation triggered by rhodium(III)-catalyzed sequential C(sp(2))–H activation and C(sp(3))–H amination
por: Song, Liangliang, et al.
Publicado: (2019)

Manganese-catalyzed benzylic C(sp(3))–H amination for late-stage functionalization
por: Clark, Joseph R., et al.
Publicado: (2018)

Chemoselective Activation of sp(3) vs sp(2) C–H Bonds with Pd(II)
por: Curto, John M., et al.
Publicado: (2014)

Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp(3))–H bonds with acetonitrile
por: Liu, Yongbing, et al.
Publicado: (2016)

Assembly of Tetrahydroquinolines and 2-Benzazepines by Pd-Catalyzed Cycloadditions Involving the Activation of C(sp(3))–H Bonds
por: Vidal, Xandro, et al.
Publicado: (2021)

Artificial Metalloenzyme-Catalyzed Enantioselective Amidation via Nitrene Insertion in Unactivated C(sp(3))–H Bonds
por: Yu, Kun, et al.
Publicado: (2023)

Efficient Amination of Activated and Non‐Activated C(sp(3))−H Bonds with a Simple Iron–Phenanthroline Catalyst
por: Jarrige, Lucie, et al.
Publicado: (2021)

Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp(3))−H Bond Insertion
por: Díaz‐Jiménez, Àlex, et al.
Publicado: (2022)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Cannot write session to /tmp/vufind_sessions/sess_dfsc6jmds93nib087rgq1fjdkq