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Detection and Verification of a Key Intermediate in an Enantioselective Peptide Catalyzed Acylation Reaction
Until now, the intermediate responsible for the acyl transfer of a highly enantioselective tetrapeptide organocatalyst for the kinetic resolution of trans-cycloalkane-1,2-diols has never been directly observed. It was proposed computationally that a π-methylhistidine moiety is acylated as an interme...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571696/ https://www.ncbi.nlm.nih.gov/pubmed/36234884 http://dx.doi.org/10.3390/molecules27196351 |