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Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery
Sodium-ion batteries (SIBs) have attracted increasing interest as promising candidates for large-scale energy storage due to their low cost, natural abundance and similar chemical intercalation mechanism with lithium-ion batteries. However, achieving superior rate capability and long-life for SIBs r...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571770/ https://www.ncbi.nlm.nih.gov/pubmed/36234839 http://dx.doi.org/10.3390/molecules27196303 |
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author | Chen, Yi Qi, Haimei Sun, Jie Lei, Zhibin Liu, Zong-Huai Hu, Peng He, Xuexia |
author_facet | Chen, Yi Qi, Haimei Sun, Jie Lei, Zhibin Liu, Zong-Huai Hu, Peng He, Xuexia |
author_sort | Chen, Yi |
collection | PubMed |
description | Sodium-ion batteries (SIBs) have attracted increasing interest as promising candidates for large-scale energy storage due to their low cost, natural abundance and similar chemical intercalation mechanism with lithium-ion batteries. However, achieving superior rate capability and long-life for SIBs remains a major challenge owing to the limitation of favorable anode materials selection. Herein, an elegant one-step solvothermal method was used to synthesize VS(4) nanorods and VS(4) nanorods/reduced graphene oxide (RGO) nanocomposites. The effects of ethylene carbonate/diethyl carbonate(EC/DEC), ethylene carbonate/dimethyl carbonate(EC/DMC), and tetraethylene glycol dimethyl ether (TEGDME) electrolytes on the electrochemical properties of VS(4) nanorods were investigated. The VS(4) nanorods electrodes exhibit high specific capacity in EC/DMC electrolytes. A theoretical calculation confirms the advance of EC/DMC electrolytes for VS(4) nanorods. Significantly, the discharge capacity of VS(4)/RGO nanocomposites remains 100 mAh/g after 2000 cycles at a large current density of 2 A/g, indicating their excellent cycling stability. The nanocomposites can improve the electronic conductivity and reduce the Na(+) diffusion energy barrier, thereby effectively improving the sodium storage performance of the hybrid material. This work offers great potential for exploring promising anode materials for electrochemical applications. |
format | Online Article Text |
id | pubmed-9571770 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-95717702022-10-17 Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery Chen, Yi Qi, Haimei Sun, Jie Lei, Zhibin Liu, Zong-Huai Hu, Peng He, Xuexia Molecules Article Sodium-ion batteries (SIBs) have attracted increasing interest as promising candidates for large-scale energy storage due to their low cost, natural abundance and similar chemical intercalation mechanism with lithium-ion batteries. However, achieving superior rate capability and long-life for SIBs remains a major challenge owing to the limitation of favorable anode materials selection. Herein, an elegant one-step solvothermal method was used to synthesize VS(4) nanorods and VS(4) nanorods/reduced graphene oxide (RGO) nanocomposites. The effects of ethylene carbonate/diethyl carbonate(EC/DEC), ethylene carbonate/dimethyl carbonate(EC/DMC), and tetraethylene glycol dimethyl ether (TEGDME) electrolytes on the electrochemical properties of VS(4) nanorods were investigated. The VS(4) nanorods electrodes exhibit high specific capacity in EC/DMC electrolytes. A theoretical calculation confirms the advance of EC/DMC electrolytes for VS(4) nanorods. Significantly, the discharge capacity of VS(4)/RGO nanocomposites remains 100 mAh/g after 2000 cycles at a large current density of 2 A/g, indicating their excellent cycling stability. The nanocomposites can improve the electronic conductivity and reduce the Na(+) diffusion energy barrier, thereby effectively improving the sodium storage performance of the hybrid material. This work offers great potential for exploring promising anode materials for electrochemical applications. MDPI 2022-09-24 /pmc/articles/PMC9571770/ /pubmed/36234839 http://dx.doi.org/10.3390/molecules27196303 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Chen, Yi Qi, Haimei Sun, Jie Lei, Zhibin Liu, Zong-Huai Hu, Peng He, Xuexia Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title | Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title_full | Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title_fullStr | Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title_full_unstemmed | Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title_short | Synergy Effect of High-Stability of VS(4) Nanorods for Sodium Ion Battery |
title_sort | synergy effect of high-stability of vs(4) nanorods for sodium ion battery |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571770/ https://www.ncbi.nlm.nih.gov/pubmed/36234839 http://dx.doi.org/10.3390/molecules27196303 |
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