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Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior
(1) Mud pulser carbide rotors, as a core component of ground communication in crude oil exploration, are often subjected to mud erosion and acid corrosion, resulting in pitting pits on the surface, which affects the accuracy. The purpose of this study was to investigate the acid corrosion and erosio...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571873/ https://www.ncbi.nlm.nih.gov/pubmed/36234373 http://dx.doi.org/10.3390/ma15197023 |
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author | Wei, Shasha Li, Yuanyou Wang, Renxin Yang, Hu Guo, Ziming Lin, Rongchuan Huang, Qingmin Zhou, Yuhui |
author_facet | Wei, Shasha Li, Yuanyou Wang, Renxin Yang, Hu Guo, Ziming Lin, Rongchuan Huang, Qingmin Zhou, Yuhui |
author_sort | Wei, Shasha |
collection | PubMed |
description | (1) Mud pulser carbide rotors, as a core component of ground communication in crude oil exploration, are often subjected to mud erosion and acid corrosion, resulting in pitting pits on the surface, which affects the accuracy. The purpose of this study was to investigate the acid corrosion and erosion behavior of cemented carbide materials and provide a reference for the wider application of cemented carbide materials in the petrochemical industry. (2) Experimental samples of tungsten–cobalt carbide were sintered at a low pressure by powder metallurgy. The petrochemical application environment was simulated by accelerated salt spray corrosion and solid slurry erosion with the aid of acidic copper, and the experimental phenomena were analyzed by SEM (scanning electron microscope), EDS (Energy Dispersive Spectroscopy), and XRD (X-ray diffraction). (3) The experimental results show that the coercivity of the pitted cobalt-cemented tungsten carbide prepared in this study was 17.89 KA/m, and the magnetic saturation strength was 14.42 G·cm(3)/g. The corrosion rate was the fastest during the acidic copper acceleration experiments from 4 h to 16 h, and the corrosion products of WCo(3) and Co(3)O(4) were generated on the corrosion surface. The maximum erosion rate of 0.00104 in the erosion experiment corresponds to a corrosion sample with a corrosion time of 36 h. (4) Therefore, the coercive magnetic force and magnetic saturation strength could be derived from the prepared carbide hard phase grains and carbon content in the appropriate range. The corrosion product in the corrosion process slowed the corrosion rate, and a large amount of cobalt and a small amount of tungsten was lost by oxidation during the corrosion process. The corrosion time had the greatest effect on the erosion performance of the carbide, and the long corrosion time led to surface sparseness, which reduced the erosion resistance. |
format | Online Article Text |
id | pubmed-9571873 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-95718732022-10-17 Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior Wei, Shasha Li, Yuanyou Wang, Renxin Yang, Hu Guo, Ziming Lin, Rongchuan Huang, Qingmin Zhou, Yuhui Materials (Basel) Article (1) Mud pulser carbide rotors, as a core component of ground communication in crude oil exploration, are often subjected to mud erosion and acid corrosion, resulting in pitting pits on the surface, which affects the accuracy. The purpose of this study was to investigate the acid corrosion and erosion behavior of cemented carbide materials and provide a reference for the wider application of cemented carbide materials in the petrochemical industry. (2) Experimental samples of tungsten–cobalt carbide were sintered at a low pressure by powder metallurgy. The petrochemical application environment was simulated by accelerated salt spray corrosion and solid slurry erosion with the aid of acidic copper, and the experimental phenomena were analyzed by SEM (scanning electron microscope), EDS (Energy Dispersive Spectroscopy), and XRD (X-ray diffraction). (3) The experimental results show that the coercivity of the pitted cobalt-cemented tungsten carbide prepared in this study was 17.89 KA/m, and the magnetic saturation strength was 14.42 G·cm(3)/g. The corrosion rate was the fastest during the acidic copper acceleration experiments from 4 h to 16 h, and the corrosion products of WCo(3) and Co(3)O(4) were generated on the corrosion surface. The maximum erosion rate of 0.00104 in the erosion experiment corresponds to a corrosion sample with a corrosion time of 36 h. (4) Therefore, the coercive magnetic force and magnetic saturation strength could be derived from the prepared carbide hard phase grains and carbon content in the appropriate range. The corrosion product in the corrosion process slowed the corrosion rate, and a large amount of cobalt and a small amount of tungsten was lost by oxidation during the corrosion process. The corrosion time had the greatest effect on the erosion performance of the carbide, and the long corrosion time led to surface sparseness, which reduced the erosion resistance. MDPI 2022-10-10 /pmc/articles/PMC9571873/ /pubmed/36234373 http://dx.doi.org/10.3390/ma15197023 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Wei, Shasha Li, Yuanyou Wang, Renxin Yang, Hu Guo, Ziming Lin, Rongchuan Huang, Qingmin Zhou, Yuhui Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title | Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title_full | Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title_fullStr | Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title_full_unstemmed | Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title_short | Preparation of Cemented Carbide and Study of Copper-Accelerated Salt Spray Corrosion and Erosion Behavior |
title_sort | preparation of cemented carbide and study of copper-accelerated salt spray corrosion and erosion behavior |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571873/ https://www.ncbi.nlm.nih.gov/pubmed/36234373 http://dx.doi.org/10.3390/ma15197023 |
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