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Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers

This paper investigates the possibility of integrating the combination of nanofillers, titanium dioxide (TiO(2)) and carbon nanotubes (CNT) into the thermoplastic polymer matrix. This combination of fillers can possibly modify the physico-chemical properties of composites compared to the pure polyme...

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Detalles Bibliográficos
Autores principales: Marković, Marijan-Pere, Cingesar, Ivan Karlo, Keran, Laura, Prlić, Domagoj, Grčić, Ivana, Vrsaljko, Domagoj
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571915/
https://www.ncbi.nlm.nih.gov/pubmed/36234051
http://dx.doi.org/10.3390/ma15196713
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author Marković, Marijan-Pere
Cingesar, Ivan Karlo
Keran, Laura
Prlić, Domagoj
Grčić, Ivana
Vrsaljko, Domagoj
author_facet Marković, Marijan-Pere
Cingesar, Ivan Karlo
Keran, Laura
Prlić, Domagoj
Grčić, Ivana
Vrsaljko, Domagoj
author_sort Marković, Marijan-Pere
collection PubMed
description This paper investigates the possibility of integrating the combination of nanofillers, titanium dioxide (TiO(2)) and carbon nanotubes (CNT) into the thermoplastic polymer matrix. This combination of fillers can possibly modify the physico-chemical properties of composites compared to the pure polymer matrix. The composites were blended using the extrusion method. The composite filament produced was used to manufacture static mixers on a 3D printer using the additive manufacturing technology fused filament fabrication (FFF). The aim of this work was to inspect the influence of the filler addition on the thermal and mechanical properties of glycol-modified polyethylene terephthalate (PET-G) polymer composites. The fillers were added to the PET-G polymer matrix in several ratios. Tensile test results showed an increase in the overall strength and decrease in the elongation at break of the material. Melt flow rate (MFR) showed a decrease in the viscosity with the initial filler addition and reaching a plateau after 2 wt% filler was added. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed minor changes in the thermal properties. Scanning electron microscope (SEM) results showed homogenous distribution of the filler in the matrix and strong filler–matrix adhesion. The results indicate suitable properties of new functional composites for the 3D printing of static mixers for application in tubular reactors.
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spelling pubmed-95719152022-10-17 Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers Marković, Marijan-Pere Cingesar, Ivan Karlo Keran, Laura Prlić, Domagoj Grčić, Ivana Vrsaljko, Domagoj Materials (Basel) Article This paper investigates the possibility of integrating the combination of nanofillers, titanium dioxide (TiO(2)) and carbon nanotubes (CNT) into the thermoplastic polymer matrix. This combination of fillers can possibly modify the physico-chemical properties of composites compared to the pure polymer matrix. The composites were blended using the extrusion method. The composite filament produced was used to manufacture static mixers on a 3D printer using the additive manufacturing technology fused filament fabrication (FFF). The aim of this work was to inspect the influence of the filler addition on the thermal and mechanical properties of glycol-modified polyethylene terephthalate (PET-G) polymer composites. The fillers were added to the PET-G polymer matrix in several ratios. Tensile test results showed an increase in the overall strength and decrease in the elongation at break of the material. Melt flow rate (MFR) showed a decrease in the viscosity with the initial filler addition and reaching a plateau after 2 wt% filler was added. Differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) showed minor changes in the thermal properties. Scanning electron microscope (SEM) results showed homogenous distribution of the filler in the matrix and strong filler–matrix adhesion. The results indicate suitable properties of new functional composites for the 3D printing of static mixers for application in tubular reactors. MDPI 2022-09-27 /pmc/articles/PMC9571915/ /pubmed/36234051 http://dx.doi.org/10.3390/ma15196713 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Marković, Marijan-Pere
Cingesar, Ivan Karlo
Keran, Laura
Prlić, Domagoj
Grčić, Ivana
Vrsaljko, Domagoj
Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title_full Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title_fullStr Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title_full_unstemmed Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title_short Thermal and Mechanical Characterization of the New Functional Composites Used for 3D Printing of Static Mixers
title_sort thermal and mechanical characterization of the new functional composites used for 3d printing of static mixers
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571915/
https://www.ncbi.nlm.nih.gov/pubmed/36234051
http://dx.doi.org/10.3390/ma15196713
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