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First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties

We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of...

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Detalles Bibliográficos
Autores principales: Brégier, Frédérique, Sol, Vincent, Champavier, Yves, Galmiche, Laurent, Allain, Clémence, Audebert, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571928/
https://www.ncbi.nlm.nih.gov/pubmed/36235234
http://dx.doi.org/10.3390/molecules27196698
Descripción
Sumario:We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of energy transfer between both partners.