First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties

We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of...

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Detalles Bibliográficos
Autores principales: Brégier, Frédérique, Sol, Vincent, Champavier, Yves, Galmiche, Laurent, Allain, Clémence, Audebert, Pierre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571928/
https://www.ncbi.nlm.nih.gov/pubmed/36235234
http://dx.doi.org/10.3390/molecules27196698
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author Brégier, Frédérique
Sol, Vincent
Champavier, Yves
Galmiche, Laurent
Allain, Clémence
Audebert, Pierre
author_facet Brégier, Frédérique
Sol, Vincent
Champavier, Yves
Galmiche, Laurent
Allain, Clémence
Audebert, Pierre
author_sort Brégier, Frédérique
collection PubMed
description We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of energy transfer between both partners.
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spelling pubmed-95719282022-10-17 First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties Brégier, Frédérique Sol, Vincent Champavier, Yves Galmiche, Laurent Allain, Clémence Audebert, Pierre Molecules Communication We have prepared the first example of a porphyrin linked to an heptazine photoactive antenna. The two entities, linked with an alkyl spacer, demonstrate the activity of both active moieties. While they behave electrochemically independantly, on the other hand the spectroscopy shows the existence of energy transfer between both partners. MDPI 2022-10-08 /pmc/articles/PMC9571928/ /pubmed/36235234 http://dx.doi.org/10.3390/molecules27196698 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Brégier, Frédérique
Sol, Vincent
Champavier, Yves
Galmiche, Laurent
Allain, Clémence
Audebert, Pierre
First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title_full First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title_fullStr First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title_full_unstemmed First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title_short First Example of a Heptazine-Porphyrin Dyad; Synthesis and Spectroscopic Properties
title_sort first example of a heptazine-porphyrin dyad; synthesis and spectroscopic properties
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9571928/
https://www.ncbi.nlm.nih.gov/pubmed/36235234
http://dx.doi.org/10.3390/molecules27196698
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