Cargando…

Deracemisation and stereoinversion by a nanoconfined bidirectional enzyme cascade: dual control by electrochemistry and selective metal ion activation

The unique ability of the ‘electrochemical leaf’ (e-Leaf) to drive and control nanoconfined enzyme cascades bidirectionally, while directly monitoring their rate in real-time as electrical current, is exploited to achieve deracemisation and stereoinversion of secondary alcohols using a single electr...

Descripción completa

Detalles Bibliográficos
Autores principales: Cheng, Beichen, Heath, Rachel S., Turner, Nicholas J., Armstrong, Fraser A., Megarity, Clare F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9578339/
https://www.ncbi.nlm.nih.gov/pubmed/36178369
http://dx.doi.org/10.1039/d2cc03638j