Polyelectrolyte/Surfactant Mixtures: A Pathway to Smart Foams

[Image: see text] This review deals with liquid foams stabilized by polyelectrolyte/surfactant (PS) complexes in aqueous solution. It briefly reviews all the important aspects of foam physics at several scales, from interfaces to macroscopic foams, needed to understand the basics of these complex systems, focusing on those particular aspects of foams stabilized by PS mixtures. The final section includes a few examples of smart foams based on PS complexes that have been reported recently in the literature. These PS complexes open an opportunity to develop new intelligent dispersed materials with potential in many fields, such as oil industry, environmental remediation, and pharmaceutical industry, among others. However, there is much work to be done to understand the mechanism involved in the stabilization of foams with PS complexes. Understanding those underlying mechanisms is vital to successfully formulate smart systems. This review is written in the hope of stimulating further work in the physics of PS foams and, particularly, in the search for responsive foams based on polymer-surfactant mixtures.