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Stability of Carbocyclic Phosphinyl Radicals: Effect of Ring Size, Delocalization, and Sterics
[Image: see text] In this computational study, we report on the stability of cyclic phosphinyl radicals with an aim for a systematical assessment of stabilization effects. The radical stabilization energies (RSEs) were calculated using isodesmic reactions for a large number of carbocyclic radicals p...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9583709/ https://www.ncbi.nlm.nih.gov/pubmed/36197796 http://dx.doi.org/10.1021/acs.inorgchem.2c01968 |