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How Nature Makes O(2): an Electronic Level Mechanism for Water Oxidation in Photosynthesis

[Image: see text] In this paper, we combine broken symmetry density functional calculations and electron paramagnetic resonance analysis to obtain the electronic structure of the penultimate S(3) state of nature’s water-oxidizing complex and determine the electronic pathway of O–O bond formation. An...

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Detalles Bibliográficos
Autores principales: Rummel, Felix, O’Malley, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9589598/
https://www.ncbi.nlm.nih.gov/pubmed/36206029
http://dx.doi.org/10.1021/acs.jpcb.2c06374