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Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction

In this work, a CdS/BiVO(4) step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-...

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Autores principales: Zhang, Yifeng, Sun, Haorong, Gao, Feixue, Zhang, Shuo, Han, Qingzhi, Li, Jing, Fang, Ming, Cai, Yawen, Hu, Baowei, Tan, Xiaoli, Wang, Xiangke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9590271/
https://www.ncbi.nlm.nih.gov/pubmed/36320635
http://dx.doi.org/10.34133/2022/9790320
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author Zhang, Yifeng
Sun, Haorong
Gao, Feixue
Zhang, Shuo
Han, Qingzhi
Li, Jing
Fang, Ming
Cai, Yawen
Hu, Baowei
Tan, Xiaoli
Wang, Xiangke
author_facet Zhang, Yifeng
Sun, Haorong
Gao, Feixue
Zhang, Shuo
Han, Qingzhi
Li, Jing
Fang, Ming
Cai, Yawen
Hu, Baowei
Tan, Xiaoli
Wang, Xiangke
author_sort Zhang, Yifeng
collection PubMed
description In this work, a CdS/BiVO(4) step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions, which allows CdS/BiVO(4) to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BiVO(4). Experimental results such as radical quenching experiments and electron spin resonance show that U(VI) is rapidly oxidized by photoholes/(•)OH to insoluble UO(2)(OH)(2) after being reduced to U(IV) by photoelectrons/(•)O(2)(−), which precisely avoids the depletion of electron sacrificial agents. The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis. This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts.
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spelling pubmed-95902712022-10-31 Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction Zhang, Yifeng Sun, Haorong Gao, Feixue Zhang, Shuo Han, Qingzhi Li, Jing Fang, Ming Cai, Yawen Hu, Baowei Tan, Xiaoli Wang, Xiangke Research (Wash D C) Research Article In this work, a CdS/BiVO(4) step-scheme (S-scheme) heterojunction with self-photothermally enhanced photocatalytic effect was synthesized and applied for efficient U(VI) photoextraction. Characterizations such as transient absorption spectroscopy and Tafel test together confirmed the formation of S-scheme heterojunctions, which allows CdS/BiVO(4) to avoid photocorrosion while retaining the strong reducing capacity of CdS and the oxidizing capacity of BiVO(4). Experimental results such as radical quenching experiments and electron spin resonance show that U(VI) is rapidly oxidized by photoholes/(•)OH to insoluble UO(2)(OH)(2) after being reduced to U(IV) by photoelectrons/(•)O(2)(−), which precisely avoids the depletion of electron sacrificial agents. The rapid recombination of electron-hole pairs triggered by the S-scheme heterojunction is found to release large amounts of heat and accelerate the photocatalysis. This work offers a new enhanced strategy for photocatalytic uranium extraction and presents a direction for the design and development of new photocatalysts. AAAS 2022-10-11 /pmc/articles/PMC9590271/ /pubmed/36320635 http://dx.doi.org/10.34133/2022/9790320 Text en Copyright © 2022 Yifeng Zhang et al. https://creativecommons.org/licenses/by/4.0/Exclusive Licensee Science and Technology Review Publishing House. Distributed under a Creative Commons Attribution License (CC BY 4.0).
spellingShingle Research Article
Zhang, Yifeng
Sun, Haorong
Gao, Feixue
Zhang, Shuo
Han, Qingzhi
Li, Jing
Fang, Ming
Cai, Yawen
Hu, Baowei
Tan, Xiaoli
Wang, Xiangke
Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title_full Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title_fullStr Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title_full_unstemmed Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title_short Insights into Photothermally Enhanced Photocatalytic U(VI) Extraction by a Step-Scheme Heterojunction
title_sort insights into photothermally enhanced photocatalytic u(vi) extraction by a step-scheme heterojunction
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9590271/
https://www.ncbi.nlm.nih.gov/pubmed/36320635
http://dx.doi.org/10.34133/2022/9790320
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