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Neutral and Cationic Complexes of Silicon(IV) Halides with Phosphine Ligands
[Image: see text] The reaction of SiI(4) and PMe(3) in n-hexane produced the yellow salt, [SiI(3)(PMe(3))(2)]I, confirmed from its X-ray structure, containing a trigonal bipyramidal cation with trans-phosphines. This contrasts with the six-coordination found in (the known) trans-[SiX(4)(PMe(3))(2)]...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9597660/ https://www.ncbi.nlm.nih.gov/pubmed/36222839 http://dx.doi.org/10.1021/acs.inorgchem.2c02949 |