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Mesoporous multi-shelled hollow resin nanospheres with ultralow thermal conductivity

Hollow nanostructures exhibit enclosed or semi-enclosed spaces inside and the consequent features of restricting molecular motion, which is crucial for intrinsic physicochemical properties. Herein, we developed a new configuration of hollow nanostructures with more than three layers of shells and si...

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Detalles Bibliográficos
Autores principales: Yuan, Ruilin, Wang, Chun, Chen, Long, Cheng, Han, Bi, Wentuan, Yan, Wensheng, Xie, Yi, Wu, Changzheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9600400/
https://www.ncbi.nlm.nih.gov/pubmed/36349103
http://dx.doi.org/10.1039/d2sc03659b
Descripción
Sumario:Hollow nanostructures exhibit enclosed or semi-enclosed spaces inside and the consequent features of restricting molecular motion, which is crucial for intrinsic physicochemical properties. Herein, we developed a new configuration of hollow nanostructures with more than three layers of shells and simultaneously integrated mesopores on every shell. The novel interior configuration expresses the characteristics of periodic interfaces and abundant mesopores. Benefiting from the suppression of gas molecule convection by boundary scattering, the thermal conductivity of mesoporous multi-shelled hollow resin nanospheres reaches 0.013 W m(−1) K(−1) at 298 K. The designed interior mesostructural configuration of hollow nanostructures provides an ideal platform to clarify the influence of nanostructure design on intrinsic physicochemical properties and propels the development of hollow nanostructures.