Cargando…
Radical generation enabled by photoinduced N–O bond fragmentation
Recent advances in synthetic chemistry have seen a resurgence in the development of methods for visible light-mediated radical generation. Herein, we report the development of a photoactive ester based on a quinoline N-oxide core structure, that provides a strong oxidant in its excited state. The he...
Autores principales: | McClain, Edward J., Wortman, Alan K., Stephenson, Corey R. J. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9600408/ https://www.ncbi.nlm.nih.gov/pubmed/36349097 http://dx.doi.org/10.1039/d2sc02953g |
Ejemplares similares
-
Boosting cancer therapy efficiency via photoinduced radical production
por: Liu, Zhiyong, et al.
Publicado: (2021) -
Photoinduced transition-metal- and external-photosensitizer-free intramolecular aryl rearrangement via C(Ar)–O bond cleavage
por: Dou, Qian, et al.
Publicado: (2020) -
Decarboxylative sulfoximination of benzoic acids enabled by photoinduced ligand-to-copper charge transfer
por: Xu, Peng, et al.
Publicado: (2022) -
Photoinduced β-fragmentation of aliphatic alcohol derivatives for forging C–C bonds
por: Gao, Yiman, et al.
Publicado: (2022) -
Enhanced photoinduced mass migration in supramolecular azopolymers by H-bond driven positional constraint
por: Borbone, Fabio, et al.
Publicado: (2021)