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Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters

Supplementary cementitious materials (SCMs) are commonly used to partially replace cements. Although it is necessary to investigate the rheological properties of the individual supplementary cementitious materials (SCMs) for understanding complex rheological behaviors of the blended mixes, the study...

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Autores principales: Rajagopalan, Sam Rajadurai, Lee, Bang-Yeon, Kang, Su-Tae
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9605141/
https://www.ncbi.nlm.nih.gov/pubmed/36295112
http://dx.doi.org/10.3390/ma15207044
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author Rajagopalan, Sam Rajadurai
Lee, Bang-Yeon
Kang, Su-Tae
author_facet Rajagopalan, Sam Rajadurai
Lee, Bang-Yeon
Kang, Su-Tae
author_sort Rajagopalan, Sam Rajadurai
collection PubMed
description Supplementary cementitious materials (SCMs) are commonly used to partially replace cements. Although it is necessary to investigate the rheological properties of the individual supplementary cementitious materials (SCMs) for understanding complex rheological behaviors of the blended mixes, the study on the investigation of rheological properties of various SCMs such as fly ash, blast-furnace slag, and silica fume, according to various solid volume fractions and prediction models is fairly limited. This study investigated the rheological properties of non-blended cementitious suspensions with Portland cement (PC), fly ash (FA), blast-furnace slag (BS), and silica fume (SF) materials in the experiments and predicted using YODEL (Yield stress mODEL) and Krieger–Dougherty’s (K–D’s) equation. Experiments were designed with various solid volume fractions ([Formula: see text]) from 0.28 to 0.44, and the rheological properties of all cementitious suspensions were noted to increase with increasing [Formula: see text] , showing an improved flowability at low [Formula: see text]. YODEL, derived from the first principles considering particle-size distributions, interparticle forces and microstructural parameters predicted the yield stress. The YODEL predictions were consistent with the experiments with a positive correlation coefficient of above 0.96. K–D’s equation with the maximum particle fractions and intrinsic viscosity as key parameters predicted the plastic viscosity. The K–D’s equation predictions match up with the experiments with a positive correlation coefficient of above 0.94. Both models showed more quantitative predictions without any fitting parameters and could be applied to any multimodal powder suspensions.
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spelling pubmed-96051412022-10-27 Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters Rajagopalan, Sam Rajadurai Lee, Bang-Yeon Kang, Su-Tae Materials (Basel) Article Supplementary cementitious materials (SCMs) are commonly used to partially replace cements. Although it is necessary to investigate the rheological properties of the individual supplementary cementitious materials (SCMs) for understanding complex rheological behaviors of the blended mixes, the study on the investigation of rheological properties of various SCMs such as fly ash, blast-furnace slag, and silica fume, according to various solid volume fractions and prediction models is fairly limited. This study investigated the rheological properties of non-blended cementitious suspensions with Portland cement (PC), fly ash (FA), blast-furnace slag (BS), and silica fume (SF) materials in the experiments and predicted using YODEL (Yield stress mODEL) and Krieger–Dougherty’s (K–D’s) equation. Experiments were designed with various solid volume fractions ([Formula: see text]) from 0.28 to 0.44, and the rheological properties of all cementitious suspensions were noted to increase with increasing [Formula: see text] , showing an improved flowability at low [Formula: see text]. YODEL, derived from the first principles considering particle-size distributions, interparticle forces and microstructural parameters predicted the yield stress. The YODEL predictions were consistent with the experiments with a positive correlation coefficient of above 0.96. K–D’s equation with the maximum particle fractions and intrinsic viscosity as key parameters predicted the plastic viscosity. The K–D’s equation predictions match up with the experiments with a positive correlation coefficient of above 0.94. Both models showed more quantitative predictions without any fitting parameters and could be applied to any multimodal powder suspensions. MDPI 2022-10-11 /pmc/articles/PMC9605141/ /pubmed/36295112 http://dx.doi.org/10.3390/ma15207044 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Rajagopalan, Sam Rajadurai
Lee, Bang-Yeon
Kang, Su-Tae
Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title_full Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title_fullStr Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title_full_unstemmed Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title_short Prediction of the Rheological Properties of Fresh Cementitious Suspensions Considering Microstructural Parameters
title_sort prediction of the rheological properties of fresh cementitious suspensions considering microstructural parameters
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9605141/
https://www.ncbi.nlm.nih.gov/pubmed/36295112
http://dx.doi.org/10.3390/ma15207044
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