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Optimization of the Pentachlorophenol Adsorption by Organo-Clays Based on Response Surface Methodology

The aim of this study is to optimize the adsorption of pentachlorophenol (PCP) using an organo-clay under the response surface methodology. The adsorbent was selected from a montmorillonite exchanged by various cations, such as Fe(3+), Al(3+), Zn(2+), Mg(2+), Na(+), and modified by bromide cetyltrim...

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Detalles Bibliográficos
Autores principales: El Mahmoudi, Soufiane, Elmchaouri, Abdellah, El kaimech, Assya, Gil, Antonio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9606915/
https://www.ncbi.nlm.nih.gov/pubmed/36295237
http://dx.doi.org/10.3390/ma15207169
Descripción
Sumario:The aim of this study is to optimize the adsorption of pentachlorophenol (PCP) using an organo-clay under the response surface methodology. The adsorbent was selected from a montmorillonite exchanged by various cations, such as Fe(3+), Al(3+), Zn(2+), Mg(2+), Na(+), and modified by bromide cetyltrimethylammonium (CTAB) as surfactant. The obtained organo-montmorillonite was characterized using several techniques, such as Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and nitrogen adsorption, performed at −196 °C. The results showed an increase in basal space from 1.65 to 1.88 nm and a decrease in the specific surface and pore volume, with an increase in pore diameter, including the presence of characteristic bands of -CH(2)- and -CH(3)- groups at 2926 and 2854 cm(−1) in the FTIR spectrum after the modification. The optimization of PCP removal by clay adsorbents is achieved using the response surface methodology (RSM) with a four-factor central composite model, including pH of solution, mass of adsorbent, contact time, and initial concentration. The results proved the validity of the regression model, wherein the adsorption capacity reaches its maximum value of 38 mg/g at a lower adsorbent mass of 20 mg, pH of 6, contact time (t(c)) of 5 h, and initial concentration of 8 mg/L.