An Efficient Cross-Linked Phosphorus-Free Flame Retardant for Epoxy Resins

[Image: see text] Epoxy resins (EPs) have been widely used due to their great physical and chemical properties, but their poor flame retardancy limits their further application. In this work, we synthesized a flame retardant containing nitrile groups and a double bond to improve the flame retardancy of EPs. In this way, multiple cross-linking reactions can occur in the EPs to confer better flame retardancy by a simple heat treatment. The UL-94 vertical combustion test, CCT, and limiting oxygen index (LOI) test were used to characterize the flame retardant properties of the cross-linked flame retardant; the results show that with the 10 wt % addition of cross-linked flame retardant, the thermosets can pass the UL-94 V-0 rating. Meanwhile, the contents reached 20 wt %, and the peak heat release rate decreased 40% compared with neat EP.