Effect of Activator and Outgoing Ligand Nature on the Catalytic Behavior of Bis(phenoxy-imine) Ti(IV) Complexes in the Polymerization of Ethylene and Its Copolymerization with Higher Olefins

A series of bis(phenoxy-imine) (FI) titanium(IV) and zirconium(IV) complexes have been synthesized. The effect of the nature of the activator (MAO, combinations Et(n)AlCl(3-n) + Bu(2)Mg and iBu(3)Al + [Ph(3)C](+)[B(C(6)F(5))(4)](−)) on the catalytic activity and properties of the resulting polymers...

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Detalles Bibliográficos
Autores principales: Gagieva, Svetlana Ch., Magomedov, Kasim F., Tuskaev, Vladislav A., Bogdanov, Vyacheslav S., Kurmaev, Dmitrii A., Golubev, Evgenii K., Denisov, Gleb L., Nikiforova, Galina G., Evseeva, Maria D., Saracheno, Daniele, Buzin, Mikhail I., Dzhevakov, Pavel B., Privalov, Viktor I., Bulychev, Boris M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609217/
https://www.ncbi.nlm.nih.gov/pubmed/36297979
http://dx.doi.org/10.3390/polym14204397

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