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Irradiation Damage Independent Deuterium Retention in WMoTaNbV

High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wa...

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Detalles Bibliográficos
Autores principales: Liski, Anna, Vuoriheimo, Tomi, Jalkanen, Pasi, Mizohata, Kenichiro, Lu, Eryang, Likonen, Jari, Heino, Jouni, Heinola, Kalle, Zayachuk, Yevhen, Widdowson, Anna, Tseng, Ko-Kai, Tsai, Che-Wei, Yeh, Jien-Wei, Tuomisto, Filip, Ahlgren, Tommy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609576/
https://www.ncbi.nlm.nih.gov/pubmed/36295361
http://dx.doi.org/10.3390/ma15207296
Descripción
Sumario:High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of [Formula: see text] atoms/cm [Formula: see text]. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C.