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Irradiation Damage Independent Deuterium Retention in WMoTaNbV
High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wa...
Autores principales: | , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609576/ https://www.ncbi.nlm.nih.gov/pubmed/36295361 http://dx.doi.org/10.3390/ma15207296 |
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author | Liski, Anna Vuoriheimo, Tomi Jalkanen, Pasi Mizohata, Kenichiro Lu, Eryang Likonen, Jari Heino, Jouni Heinola, Kalle Zayachuk, Yevhen Widdowson, Anna Tseng, Ko-Kai Tsai, Che-Wei Yeh, Jien-Wei Tuomisto, Filip Ahlgren, Tommy |
author_facet | Liski, Anna Vuoriheimo, Tomi Jalkanen, Pasi Mizohata, Kenichiro Lu, Eryang Likonen, Jari Heino, Jouni Heinola, Kalle Zayachuk, Yevhen Widdowson, Anna Tseng, Ko-Kai Tsai, Che-Wei Yeh, Jien-Wei Tuomisto, Filip Ahlgren, Tommy |
author_sort | Liski, Anna |
collection | PubMed |
description | High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of [Formula: see text] atoms/cm [Formula: see text]. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C. |
format | Online Article Text |
id | pubmed-9609576 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-96095762022-10-28 Irradiation Damage Independent Deuterium Retention in WMoTaNbV Liski, Anna Vuoriheimo, Tomi Jalkanen, Pasi Mizohata, Kenichiro Lu, Eryang Likonen, Jari Heino, Jouni Heinola, Kalle Zayachuk, Yevhen Widdowson, Anna Tseng, Ko-Kai Tsai, Che-Wei Yeh, Jien-Wei Tuomisto, Filip Ahlgren, Tommy Materials (Basel) Article High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of [Formula: see text] atoms/cm [Formula: see text]. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C. MDPI 2022-10-19 /pmc/articles/PMC9609576/ /pubmed/36295361 http://dx.doi.org/10.3390/ma15207296 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Liski, Anna Vuoriheimo, Tomi Jalkanen, Pasi Mizohata, Kenichiro Lu, Eryang Likonen, Jari Heino, Jouni Heinola, Kalle Zayachuk, Yevhen Widdowson, Anna Tseng, Ko-Kai Tsai, Che-Wei Yeh, Jien-Wei Tuomisto, Filip Ahlgren, Tommy Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title | Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title_full | Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title_fullStr | Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title_full_unstemmed | Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title_short | Irradiation Damage Independent Deuterium Retention in WMoTaNbV |
title_sort | irradiation damage independent deuterium retention in wmotanbv |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609576/ https://www.ncbi.nlm.nih.gov/pubmed/36295361 http://dx.doi.org/10.3390/ma15207296 |
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