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Irradiation Damage Independent Deuterium Retention in WMoTaNbV

High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wa...

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Autores principales: Liski, Anna, Vuoriheimo, Tomi, Jalkanen, Pasi, Mizohata, Kenichiro, Lu, Eryang, Likonen, Jari, Heino, Jouni, Heinola, Kalle, Zayachuk, Yevhen, Widdowson, Anna, Tseng, Ko-Kai, Tsai, Che-Wei, Yeh, Jien-Wei, Tuomisto, Filip, Ahlgren, Tommy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609576/
https://www.ncbi.nlm.nih.gov/pubmed/36295361
http://dx.doi.org/10.3390/ma15207296
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author Liski, Anna
Vuoriheimo, Tomi
Jalkanen, Pasi
Mizohata, Kenichiro
Lu, Eryang
Likonen, Jari
Heino, Jouni
Heinola, Kalle
Zayachuk, Yevhen
Widdowson, Anna
Tseng, Ko-Kai
Tsai, Che-Wei
Yeh, Jien-Wei
Tuomisto, Filip
Ahlgren, Tommy
author_facet Liski, Anna
Vuoriheimo, Tomi
Jalkanen, Pasi
Mizohata, Kenichiro
Lu, Eryang
Likonen, Jari
Heino, Jouni
Heinola, Kalle
Zayachuk, Yevhen
Widdowson, Anna
Tseng, Ko-Kai
Tsai, Che-Wei
Yeh, Jien-Wei
Tuomisto, Filip
Ahlgren, Tommy
author_sort Liski, Anna
collection PubMed
description High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of [Formula: see text] atoms/cm [Formula: see text]. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C.
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spelling pubmed-96095762022-10-28 Irradiation Damage Independent Deuterium Retention in WMoTaNbV Liski, Anna Vuoriheimo, Tomi Jalkanen, Pasi Mizohata, Kenichiro Lu, Eryang Likonen, Jari Heino, Jouni Heinola, Kalle Zayachuk, Yevhen Widdowson, Anna Tseng, Ko-Kai Tsai, Che-Wei Yeh, Jien-Wei Tuomisto, Filip Ahlgren, Tommy Materials (Basel) Article High entropy alloys are a promising new class of metal alloys with outstanding radiation resistance and thermal stability. The interaction with hydrogen might, however, have desired (H storage) or undesired effects, such as hydrogen-induced embrittlement or tritium retention in the fusion reactor wall. High entropy alloy WMoTaNbV and bulk W samples were used to study the quantity of irradiation-induced trapping sites and properties of D retention by employing thermal desorption spectrometry, secondary ion mass spectrometry, and elastic recoil detection analysis. The D implantation was not found to create additional hydrogen traps in WMoTaNbV as it does in W, while 90 at% of implanted D is retained in WMoTaNbV, in contrast to 35 at% in W. Implantation created damage predicted by SRIM is 0.24 dpa in WMoTaNbV, calculated with a density of [Formula: see text] atoms/cm [Formula: see text]. The depth of the maximum damage was 90 nm. An effective trapping energy for D in WMoTaNbV was found to be about 1.7 eV, and the D emission temperature was close to 700 °C. MDPI 2022-10-19 /pmc/articles/PMC9609576/ /pubmed/36295361 http://dx.doi.org/10.3390/ma15207296 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liski, Anna
Vuoriheimo, Tomi
Jalkanen, Pasi
Mizohata, Kenichiro
Lu, Eryang
Likonen, Jari
Heino, Jouni
Heinola, Kalle
Zayachuk, Yevhen
Widdowson, Anna
Tseng, Ko-Kai
Tsai, Che-Wei
Yeh, Jien-Wei
Tuomisto, Filip
Ahlgren, Tommy
Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title_full Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title_fullStr Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title_full_unstemmed Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title_short Irradiation Damage Independent Deuterium Retention in WMoTaNbV
title_sort irradiation damage independent deuterium retention in wmotanbv
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609576/
https://www.ncbi.nlm.nih.gov/pubmed/36295361
http://dx.doi.org/10.3390/ma15207296
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