Highly Z-Selective Horner–Wadsworth–Emmons Olefination Using Modified Still–Gennari-Type Reagents

In this report, new, easily accessible reagents for highly Z-selective HWE reactions are presented. Alkyl di-(1,1,1,3,3,3-hexafluoroisopropyl)phosphonoacetates, structurally similar to Still–Gennari type reagents, were tested in HWE reactions with a series of various aldehydes. Very good Z-selectivi...

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Detalles Bibliográficos
Autores principales: Janicki, Ignacy, Kiełbasiński, Piotr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609750/
https://www.ncbi.nlm.nih.gov/pubmed/36296731
http://dx.doi.org/10.3390/molecules27207138

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9609750/
https://www.ncbi.nlm.nih.gov/pubmed/36296731
http://dx.doi.org/10.3390/molecules27207138

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