Investigations of Thermal, Mechanical, and Gas Barrier Properties of PA11-SiO(2) Nanocomposites for Flexible Riser Application

Acidic gas penetration through the internal pressure sheath of a flexible riser tends to cause a corrosive environment in the annulus, reducing the service life of the flexible riser. Nanoparticles can act as gas barriers in the polymer matrix to slow down the gas permeation. Herein, we prepared PA11/SiO(2) composites by the melt blending method. The effect of adding different amounts of SiO(2) to PA11 on its gas barrier properties was investigated by conducting CO(2) permeation tests between 20 °C and 90 °C. As the temperature increased, the lowest value of the permeability coefficient that could be achieved for the PA11 with different contents of SiO(2) increased. The composites PA/0.5% SiO(2) and PA/1.5% SiO(2) had the lowest permeation coefficients in the glassy state (20 °C) and rubbery state (≥50 °C). We believe that this easy-to-produce industrial PA/SiO(2) composite can be used to develop high-performance flexible riser barrier layers. It is crucial for understanding riser permeation behavior and enhancing barrier qualities.