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Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties
The improvement of optical and optoelectronic properties of the individual poly [2-methoxy-5- (2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene]–End capped with Dimethyl phenyl (OC1C10–PPV–DMP), and poly (9,9′-di- n -octylfluorenyl-2,7...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9611421/ https://www.ncbi.nlm.nih.gov/pubmed/36296603 http://dx.doi.org/10.3390/molecules27207011 |
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author | Al-Asbahi, Bandar Ali AlSalhi, Mohamad S. Jumali, Mohammad Hafizuddin Hj. Fatehmulla, Amanullah Qaid, Saif M. H. Mujamammi, Wafa Musa Ghaithan, Hamid M. |
author_facet | Al-Asbahi, Bandar Ali AlSalhi, Mohamad S. Jumali, Mohammad Hafizuddin Hj. Fatehmulla, Amanullah Qaid, Saif M. H. Mujamammi, Wafa Musa Ghaithan, Hamid M. |
author_sort | Al-Asbahi, Bandar Ali |
collection | PubMed |
description | The improvement of optical and optoelectronic properties of the individual poly [2-methoxy-5- (2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene]–End capped with Dimethyl phenyl (OC1C10–PPV–DMP), and poly (9,9′-di- n -octylfluorenyl-2,7-diyl) (F8) was revealed by blending them in ternary hybrid with optimal ratio (F8/2 wt.% MEH-PPV/2 wt.% OC1C10–PPV–DMP). All individual and optimal ternary solutions were prepared via the solution-blending method followed by depositing them onto glass and ITO substrates using spin-coating technique. The semi-crystalline phase of the ternary hybrid and the strong mixing between the conjugated polymers were evidenced by observing the X-ray diffraction patterns that related to F8 into the hybrid diffractogram. The optical and optoelectronic properties of all prepared thin films were investigated in terms of absorption and emission spectra, Commission International d′Eclairage (CIE) coordinates, and current–voltage (I-V) characterizations. Emission peaks at the entire range of visible spectrum can be revealed from the ternary hybrid of the three individual conjugated polymers, producing white emission as evidenced from the emission spectrum and CIE coordinates of the hybrid. Among all fabricated organic light-emitting diodes (OLEDs) devices, the ternary hybrid-based-OLED revealed the best performance in terms of current and turn-on voltage. |
format | Online Article Text |
id | pubmed-9611421 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-96114212022-10-28 Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties Al-Asbahi, Bandar Ali AlSalhi, Mohamad S. Jumali, Mohammad Hafizuddin Hj. Fatehmulla, Amanullah Qaid, Saif M. H. Mujamammi, Wafa Musa Ghaithan, Hamid M. Molecules Article The improvement of optical and optoelectronic properties of the individual poly [2-methoxy-5- (2-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV), poly[2-methoxy-5-(3,7-dimethyl-octyloxy)-1,4-phenylenevinylene]–End capped with Dimethyl phenyl (OC1C10–PPV–DMP), and poly (9,9′-di- n -octylfluorenyl-2,7-diyl) (F8) was revealed by blending them in ternary hybrid with optimal ratio (F8/2 wt.% MEH-PPV/2 wt.% OC1C10–PPV–DMP). All individual and optimal ternary solutions were prepared via the solution-blending method followed by depositing them onto glass and ITO substrates using spin-coating technique. The semi-crystalline phase of the ternary hybrid and the strong mixing between the conjugated polymers were evidenced by observing the X-ray diffraction patterns that related to F8 into the hybrid diffractogram. The optical and optoelectronic properties of all prepared thin films were investigated in terms of absorption and emission spectra, Commission International d′Eclairage (CIE) coordinates, and current–voltage (I-V) characterizations. Emission peaks at the entire range of visible spectrum can be revealed from the ternary hybrid of the three individual conjugated polymers, producing white emission as evidenced from the emission spectrum and CIE coordinates of the hybrid. Among all fabricated organic light-emitting diodes (OLEDs) devices, the ternary hybrid-based-OLED revealed the best performance in terms of current and turn-on voltage. MDPI 2022-10-18 /pmc/articles/PMC9611421/ /pubmed/36296603 http://dx.doi.org/10.3390/molecules27207011 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Al-Asbahi, Bandar Ali AlSalhi, Mohamad S. Jumali, Mohammad Hafizuddin Hj. Fatehmulla, Amanullah Qaid, Saif M. H. Mujamammi, Wafa Musa Ghaithan, Hamid M. Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title | Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title_full | Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title_fullStr | Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title_full_unstemmed | Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title_short | Conjugated Polymers-Based Ternary Hybrid toward Unique Photophysical Properties |
title_sort | conjugated polymers-based ternary hybrid toward unique photophysical properties |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9611421/ https://www.ncbi.nlm.nih.gov/pubmed/36296603 http://dx.doi.org/10.3390/molecules27207011 |
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