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Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η(2)-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η(2)-olefin)(2)](2) with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ligands and the η(2)-olefin is critical....
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9611579/ https://www.ncbi.nlm.nih.gov/pubmed/36296594 http://dx.doi.org/10.3390/molecules27207002 |