Carboxylic Acid Directed γ-Lactonization of Unactivated Primary C–H Bonds Catalyzed by Mn Complexes: Application to Stereoselective Natural Product Diversification

[Image: see text] Reactions that enable selective functionalization of strong aliphatic C–H bonds open new synthetic paths to rapidly increase molecular complexity and expand chemical space. Particularly valuable are reactions where site-selectivity can be directed toward a specific C–H bond by cata...

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Autores principales: Call, Arnau, Cianfanelli, Marco, Besalú-Sala, Pau, Olivo, Giorgio, Palone, Andrea, Vicens, Laia, Ribas, Xavi, Luis, Josep M., Bietti, Massimo, Costas, Miquel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9619407/
https://www.ncbi.nlm.nih.gov/pubmed/36228322
http://dx.doi.org/10.1021/jacs.2c08620

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