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Crannenols A–D, Sesquiterpenoids from the Irish Deep-Sea Soft Coral Acanella arbuscula

[Image: see text] Four undescribed sesquiterpenoids, crannenols A–D (1–4), have been isolated from CHCl(2) and MeOH extracts of the deep-sea bamboo coral Acanella arbuscula. The corals were collected from a submarine canyon on the edge of Ireland’s Porcupine Bank via a remotely operated vehicle. The...

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Detalles Bibliográficos
Autores principales: Welsch, Joshua T., Young, Ryan M., Allcock, A. Louise, Johnson, Mark P., Baker, Bill J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society and American Society of Pharmacognosy 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9623587/
https://www.ncbi.nlm.nih.gov/pubmed/36122192
http://dx.doi.org/10.1021/acs.jnatprod.2c00602
Descripción
Sumario:[Image: see text] Four undescribed sesquiterpenoids, crannenols A–D (1–4), have been isolated from CHCl(2) and MeOH extracts of the deep-sea bamboo coral Acanella arbuscula. The corals were collected from a submarine canyon on the edge of Ireland’s Porcupine Bank via a remotely operated vehicle. The structure elucidation of these (Z,E)-α-farnesene derivatives was achieved using a combination of 1D and 2D NMR, electron impact (1, 2), and electrospray ionization (3, 4) mass spectrometry.