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Kinetics and mechanism of sequential ring methyl C–H activation in cyclopentadienyl rhodium(iii) complexes
We have studied activation of the methyl C–H bonds in the cyclopentadienyl ligands of half-sandwich Rh(iii) complexes [η(5)-Cp(X)Rh(N,N′)Cl](+) by observing the dependence of sequential H/D exchange on variations in Cp(X) = Cp* (complexes 1 and 2), Me(4)PhCp (Cp(XPh), 3) or Me(4)PhPhCp (Cp(XPhPh), 4...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9623609/ https://www.ncbi.nlm.nih.gov/pubmed/36043856 http://dx.doi.org/10.1039/d2dt02079c |