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Kinetics and mechanism of sequential ring methyl C–H activation in cyclopentadienyl rhodium(iii) complexes

We have studied activation of the methyl C–H bonds in the cyclopentadienyl ligands of half-sandwich Rh(iii) complexes [η(5)-Cp(X)Rh(N,N′)Cl](+) by observing the dependence of sequential H/D exchange on variations in Cp(X) = Cp* (complexes 1 and 2), Me(4)PhCp (Cp(XPh), 3) or Me(4)PhPhCp (Cp(XPhPh), 4...

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Detalles Bibliográficos
Autores principales:	Sink, Alexandra, Banerjee, Samya, Wolny, Juliusz A., Imberti, Cinzia, Lant, Edward C., Walker, Marc, Schünemann, Volker, Sadler, Peter J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9623609/ https://www.ncbi.nlm.nih.gov/pubmed/36043856 http://dx.doi.org/10.1039/d2dt02079c

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