Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)

Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and branching has been...

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Detalles Bibliográficos
Autores principales: Flynn, Sean, Penrhyn-Lowe, Oliver B., Mckeating, Samuel, Wright, Stephen, Lomas, Sarah, Cassin, Savannah R., Chambon, Pierre, Rannard, Steve P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9627727/
https://www.ncbi.nlm.nih.gov/pubmed/36349025
http://dx.doi.org/10.1039/d2ra06578a
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author Flynn, Sean
Penrhyn-Lowe, Oliver B.
Mckeating, Samuel
Wright, Stephen
Lomas, Sarah
Cassin, Savannah R.
Chambon, Pierre
Rannard, Steve P.
author_facet Flynn, Sean
Penrhyn-Lowe, Oliver B.
Mckeating, Samuel
Wright, Stephen
Lomas, Sarah
Cassin, Savannah R.
Chambon, Pierre
Rannard, Steve P.
author_sort Flynn, Sean
collection PubMed
description Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and branching has been evaluated. Elevated temperature limits telomer length, thereby allowing a >10% reduction in the amount of telogen required to produce near identical high molecular weight branched polymers.
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spelling pubmed-96277272022-11-07 Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT) Flynn, Sean Penrhyn-Lowe, Oliver B. Mckeating, Samuel Wright, Stephen Lomas, Sarah Cassin, Savannah R. Chambon, Pierre Rannard, Steve P. RSC Adv Chemistry Transfer-dominated Branching Radical Telomerisation (TBRT) enables the production of branched polymers with step-growth backbones using radical telomerisation chemistry. By conducting identical TBRTs over a broad temperature range, the role of temperature in telomer formation and branching has been evaluated. Elevated temperature limits telomer length, thereby allowing a >10% reduction in the amount of telogen required to produce near identical high molecular weight branched polymers. The Royal Society of Chemistry 2022-11-02 /pmc/articles/PMC9627727/ /pubmed/36349025 http://dx.doi.org/10.1039/d2ra06578a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Flynn, Sean
Penrhyn-Lowe, Oliver B.
Mckeating, Samuel
Wright, Stephen
Lomas, Sarah
Cassin, Savannah R.
Chambon, Pierre
Rannard, Steve P.
Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title_full Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title_fullStr Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title_full_unstemmed Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title_short Using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (TBRT)
title_sort using temperature to modify the reaction conditions and outcomes of polymers formed using transfer-dominated branching radical telomerisation (tbrt)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9627727/
https://www.ncbi.nlm.nih.gov/pubmed/36349025
http://dx.doi.org/10.1039/d2ra06578a
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